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Fluocerite

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Halite mineral
Fluocerite-(La)
General
CategoryMineral
Formula
(repeating unit)
(La,Ce)F3
Strunz classification 03.AC.15 (03)
Dana classification 09.03.04.02 (09)
Crystal system Trigonal
Crystal class Hexagonal scalenohedral
Space group P3c1 (No. 165)
Unit cell 328.80 Å3 (Calculated from Unit Cell)
Identification
Formula mass 196.02
ColourGreenish-yellow
Crystal habit Platy, tabular
Cleavage Indistinct, Imperfect
Mohs scale hardness4-5
Luster Vitreous
Streak White
Diaphaneity Transparent to translucent
Density 5.93
Birefringence 0.006
Fluocerite-(Ce)
General
CategoryMineral
Formula
(repeating unit)
(La,Ce)F3
Strunz classification 3/A.10-20
Dana classification 9.3.4.1
Crystal system Trigonal
Crystal class Hexagonal Scalenohedral
Unit cell 320.86 Å3 (Calculated from Unit Cell)
Identification
Formula mass 196.99
ColourLight yellow; darkening to yellow- and red-brown; colourless to pale pink (transmitted light)
Crystal habit Massive, Primsatic
Cleavage Distinct/Good
Fracture Irregular/Uneven, Splintery, Sub-Conchoidal
Tenacity Brittle
Mohs scale hardness4.5-5
Luster Vitreous, Resinous, Pearly
Streak Yellow-white
Diaphaneity Transparent to translucent
Specific gravity 5.93 - 6.14
Density 5.93 - 6.14 g/cm3 (Measured)
Birefringence 0.005 - 0.007

Fluocerite, also known as tysonite, is a mineral consisting of cerium and lanthanum fluorides, with the chemical formula (Ce,La)F3.[1] [2] The end members are classified as two different mineral types depending on the cation, fluocerite-(Ce) and fluocerite-(La), corresponding respectively to lanthanum trifluoride and cerium trifluoride. Both crystallize in the trigonal system.[3]

Fluocerite-(Ce) was first described (without the Ce) in 1845 from hydrothermal veins in granite in Sweden.[4] Fluocerite-(La) was first described in 1969 from the type locality in central Kazakhstan.[3] The name tysonite was given in 1880 to the same type of mineral found in Colorado.[5] [6] Tysonite-type structure is used for rare-earth fluorides with the P3c1 space group structure.[7]

References

[edit ]
  1. ^ "Fluocerite-(La) Mineral Data". webmineral.com. Retrieved 2021年02月12日.
  2. ^ "Fluocerite-(Ce) Mineral Data". webmineral.com. Retrieved 2021年02月12日.
  3. ^ a b "Fluocerite-(La)". www.mindat.org. Retrieved 2021年02月12日.
  4. ^ "Fluocerite-(Ce)". www.mindat.org. Retrieved 2021年02月12日.
  5. ^ Geijer, Per (1921年01月01日). "On Fluocerite and Tysonite". Geologiska Föreningen i Stockholm Förhandlingar. 43 (1–2): 19–23. doi:10.1080/11035892109443886. ISSN 0016-786X.
  6. ^ Allen, Oscar D., and W. J. Comstock. "Bastnaesite and tysonite from Colorado." American Journal of Science 3.113 (1880): 390-393.
  7. ^ Dudney, Nancy J.; West, William C.; Nanda, Jagjit (2015年07月09日). Handbook Of Solid State Batteries (Second ed.). World Scientific. ISBN 978-981-4651-91-2.
Salts and covalent derivatives of the fluoride ion
HF ?HeF2
FrF RaF2   LrF3 Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
PF6, AsF6, SbF6 compounds
AlF2−5, AlF3−6 compounds
chlorides, bromides, iodides
and pseudohalogenides
SiF2−6, GeF2−6 compounds
Oxyfluorides
Organofluorides
with transition metal,
lanthanide, actinide, ammonium
nitric acids
bifluorides
thionyl, phosphoryl,
and iodosyl

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