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Radon hexafluoride

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Radon hexafluoride
Names
IUPAC name
Radon hexafluoride
Identifiers
3D model (JSmol)
ChemSpider
  • InChI=1S/F6Rn/c1-7(2,3,4,5)6
    Key: AONZSGXJYUJATR-UHFFFAOYSA-N
  • F[Rn](F)(F)(F)(F)F
Properties
F6Rn
Molar mass 336 g·mol−1
Related compounds
Related compounds
Xenon hexafluoride
Krypton hexafluoride
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Chemical compound

Radon hexafluoride is a binary chemical compound of radon and fluorine with the chemical formula RnF
6
.[1] [2] [3] This is still a hypothetical compound that has not been synthesized so far.

Potential properties

[edit ]

The compound is calculated to be less stable than radon difluoride. Radon hexafluoride is expected to have an octahedral molecular geometry, unlike the C3v of xenon hexafluoride.[4] [5]

The Rn-F bonds in radon hexafluoride is predicted to be shorter and more stable compared to Xe-F bonds in xenon hexafluoride.[5]

References

[edit ]
  1. ^ "Relativistic Research - CATCO". s3.smu.edu. Retrieved 28 April 2023.
  2. ^ Malli, G. L. (2001年03月12日). "Relativistic all-electron Dirac–Fock calculations on RnF6 and its ions". Journal of Molecular Structure: THEOCHEM. 537 (1): 71–77. doi:10.1016/S0166-1280(00)00663-1. ISSN 0166-1280.
  3. ^ Filatov, Michael; Cremer, Dieter (27 February 2003). "Bonding in radon hexafluoride: An unusual relativistic problem?". Physical Chemistry Chemical Physics . 5 (6): 1103–1105. Bibcode:2003PCCP....5.1103F. doi:10.1039/B212460M. ISSN 1463-9084 . Retrieved 28 April 2023.
  4. ^ Seppelt, Konrad (2015年01月28日). "Molecular Hexafluorides". Chemical Reviews. 115 (2): 1296–1306. doi:10.1021/cr5001783. ISSN 0009-2665. PMID 25418862.
  5. ^ a b Kang, Jaeeun; Park, Ina; Shim, Ji Hoon; Kim, Duck Young; Um, Wooyong (18 February 2023). "Prediction of stable radon fluoride molecules and geometry optimization using first-principles calculations". Scientific Reports . 13 (1): 2898. Bibcode:2023NatSR..13.2898K. doi:10.1038/s41598-023-29313-5. ISSN 2045-2322. PMC 9938903 . PMID 36801928.
Known binary hexafluorides
Chalcogen binary hexafluorides
Noble gas binary hexafluorides
Transition metal binary hexafluorides
Actinide binary hexafluorides
Predicted binary hexafluorides
Noble gas binary hexafluorides
Transition metal binary hexafluorides
Actinide binary hexafluorides
Salts and covalent derivatives of the fluoride ion
HF ?HeF2
FrF RaF2   LrF3 Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
Helium compounds
Neon compounds
Argon compounds
Krypton compounds
Xenon compounds
Xe(0)
Xe(I)
Xe(II)
Xe(IV)
Xe(VI)
Xe(VIII)
Radon compounds
Rn(II)
Rn(IV)
Rn(VI)
Oganesson compounds
(predicted)
Og(0)
  • Og2
  • OgH+
Og(II)
  • OgF2
  • OgCl2
  • OgO
Og(IV)
  • OgF4
  • OgO2
  • OgTs4
Og(VI)
  • OgF6


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