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Avogadrite

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Avogadrite
Ferruccite (white) on avogadrite (yellow-brownish), picture size: 5 mm
General
CategoryHalide mineral
Formula
(repeating unit)
(K,Cs)BF4
IMA symbol Avg[1]
Strunz classification 3.CA.10
Crystal system Orthorhombic
Crystal class Dipyramidal (mmm)
H-M symbol: (2/m 2/m 2/m)
Space group Pnma
Unit cell a = 8.6588, b = 5.48
c = 7.0299 [Å]; Z = 4
Identification
ColorColorless to white, yellowish to reddish
Crystal habit Tabular to platy octagonal crystals, tiny crystals, elongate
Luster Vitreous, greasy
Diaphaneity Translucent
Specific gravity 2.9
Optical propertiesBiaxial (-)
Refractive index nα = 1.3239, nβ = 1.3245, nγ = 1.3247
Birefringence δ = 0.001
2V angle 75°(meas), 58° (calc)
Other characteristicsBitter taste
References[2] [3] [4]

Avogadrite ((K,Cs)BF4) is a potassium-caesium tetrafluoroborate in the halide class. Avogadrite crystallizes in the orthorhombic system (space group Pnma) with cell parameters a 8.66 Å, b 5.48 Å and c Å 7.03.

History

[edit ]

The mineral was discovered by the Italian mineralogist Ferruccio Zambonini in 1926. He analyzed several samples from the volcanic fumaroles close to Mount Vesuvius and from the Lipari islands. In nature, it can only be found as a sublimation product around volcanic fumaroles.[2] He named it after the Italian scientist Amedeo Avogadro (1776–1856).[5]

Bibliography

[edit ]
  • Palache, P.; Berman H.; Frondel, C. (1960). "Dana's System of Mineralogy, Volume II: Halides, Nitrates, Borates, Carbonates, Sulfates, Phosphates, Arsenates, Tungstates, Molybdates, Etc. (Seventh Edition)" John Wiley and Sons, Inc., New York, pp. 97-98.

References

[edit ]
  1. ^ Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine. 85 (3): 291–320. Bibcode:2021MinM...85..291W. doi:10.1180/mgm.2021.43 . S2CID 235729616.
  2. ^ a b "Handbook of Mineralogy: Avogadrite" (PDF). The Mineralogical Society of America. Archived from the original (PDF) on 2012年02月18日. Retrieved 2010年01月09日.
  3. ^ Avogadrite on Mindat.org
  4. ^ Avogadrite data on Webmin
  5. ^ Zambonini, Ferruccio (1926). "Sulla presenza, tra i prodotti dell'attuale attività del Vesuvio, di una varietà cesifera del fluoborato di potassio, (On the presence, among the products of Vesuvius, of a caesium-bearing variety of potassium fluoborate), Rend. Accad. Lincei". 6 (III): 644–649. {{cite journal}}: Cite journal requires |journal= (help)
Wikimedia Commons has media related to Avogadrite .
Salts and covalent derivatives of the fluoride ion
HF ?HeF2
FrF RaF2   LrF3 Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
PF6, AsF6, SbF6 compounds
AlF2−5, AlF3−6 compounds
chlorides, bromides, iodides
and pseudohalogenides
SiF2−6, GeF2−6 compounds
Oxyfluorides
Organofluorides
with transition metal,
lanthanide, actinide, ammonium
nitric acids
bifluorides
thionyl, phosphoryl,
and iodosyl
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