WebElements logo Yttrium - 39Y
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  • ๐Ÿ‡ฌ๐Ÿ‡ง Yttrium
  • ๐Ÿ‡บ๐Ÿ‡ฆ Iั‚ั€ั–ะน
  • ๐Ÿ‡จ๐Ÿ‡ณ ้‡”
  • ๐Ÿ‡ณ๐Ÿ‡ฑ Yttrium
  • ๐Ÿ‡ซ๐Ÿ‡ท Yttrium
  • ๐Ÿ‡ฉ๐Ÿ‡ช Yttrium
  • ๐Ÿ‡ฎ๐Ÿ‡ฑ ืื™ื˜ืจื™ื•ื
  • ๐Ÿ‡ฎ๐Ÿ‡น Ittrio
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  • ๐Ÿ‡ต๐Ÿ‡น Ítrio
  • ๐Ÿ‡ช๐Ÿ‡ธ Ytrio
  • ๐Ÿ‡ธ๐Ÿ‡ช Yttrium
  • ๐Ÿ‡ท๐Ÿ‡บ ะ˜ั‚ั‚ั€ะธะน

Yttrium atoms have 39 electrons and the shell structure is 2.8.18.9.2.

The ground state electron configuration of ground state gaseous neutral yttrium is [Kr].4d1.5s2 and the term symbol is 2D3/2.

Kossel shell structure of yttrium
Schematic electronic configuration of yttrium.
Kossel shell structure of yttrium
The Kossel shell structure of yttrium.

Atomic spectrum

A representation of the atomic spectrum of yttrium.

Ionisation Energies and electron affinity

The electron affinity of yttrium is 29.6 kJ mol‑1. The ionisation energies of yttrium are given below.

Ionisation energies of yttrium
Ionisation energy number Enthalpy / kJ mol‑1
1st 599.87
2nd 1179.40
3rd 1980.30
4th 5847.7
5th 7270
6th 8818
7th 10620
8th 12250
9th 14050
10th 17920
11th 19860
12th 36090
13th 39900
14th 44700
15th 49400
16th 53900
17th 60200
18th 65300
19th 70700
20th 76200
21st 81700
Ionisation energies of yttrium
Ionisation energies of yttrium.
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Effective Nuclear Charges

The following are "Clementi-Raimondi" effective nuclear charges, Zeff. Follow the hyperlinks for more details and for graphs in various formats.

Effective nuclear charges for yttrium
1s 38.18
2s 28.62 2p 35.00
3s 23.55 3p 23.09 3d 25.40
4s 14.26 4p 12.75 4d 15.96 4f (no data)
5s 6.26 5p (no data) 5d (no data)
6s (no data) 6p (no data)
7s

References

These effective nuclear charges, Zeff, are adapted from the following references:

  1. E. Clementi and D.L.Raimondi, J. Chem. Phys. 1963, 38, 2686.
  2. E. Clementi, D.L.Raimondi, and W.P. Reinhardt, J. Chem. Phys. 1967, 47, 1300.

Electron binding energies

Electron binding energies for yttrium. All values of electron binding energies are given in eV. The binding energies are quoted relative to the vacuum level for rare gases and H2, N2, O2, F2, and Cl2 molecules; relative to the Fermi level for metals; and relative to the top of the valence band for semiconductors.
Label Orbital eV [literature reference]
K 1s 17038 [1]
L I2s 2373 [1]
L II2p1/2 2156 [1]
L III2p3/2 2080 [1]
M I3s 392 [2, values derived from reference 1]
M II3p1/2 310.6 [2]
M III3p3/2 298.8 [2]
M IV3d3/2 157.7 [3]
M V3d5/2 155.8 [3]
N I4s 43.8 [2]
N II4p1/2 24.4 [2]
N III4p3/2 23.1 [2]

Notes

I am grateful to Gwyn Williams (Jefferson Laboratory, Virginia, USA) who provided the electron binding energy data. The data are adapted from references 1-3. They are tabulated elsewhere on the WWW (reference 4) and in paper form (reference 5).

References

  1. J. A. Bearden and A. F. Burr, "Reevaluation of X-Ray Atomic Energy Levels," Rev. Mod. Phys., 1967, 39, 125.
  2. M. Cardona and L. Ley, Eds., Photoemission in Solids I: General Principles (Springer-Verlag, Berlin) with additional corrections, 1978.
  3. Gwyn Williams WWW table of values
  4. D.R. Lide, (Ed.) in Chemical Rubber Company handbook of chemistry and physics , CRC Press, Boca Raton, Florida, USA, 81st edition, 2000.
  5. J. C. Fuggle and N. Mårtensson, "Core-Level Binding Energies in Metals," J. Electron Spectrosc. Relat. Phenom., 1980, 21, 275.

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