WebElements logo Einsteinium - 99Es
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Einsteinium atoms have 99 electrons and the shell structure is 2.8.18.32.29.8.2.

The ground state electron configuration of ground state gaseous neutral einsteinium is [Rn].5f11.7s2 and the term symbol is 5I15/2.

Kossel shell structure of einsteinium
Schematic electronic configuration of einsteinium.
Kossel shell structure of einsteinium
The Kossel shell structure of einsteinium.

Atomic spectrum

A representation of the atomic spectrum of einsteinium.

Ionisation Energies and electron affinity

The electron affinity of einsteinium is (no data) kJ mol‑1. The ionisation energies of einsteinium are given below.

Ionisation energies of einsteinium
Ionisation energy number Enthalpy / kJ mol‑1
1st 614.38
2nd 1180
3rd 2190
4th 3740
5th 5220
6th 6850
7th 9360
8th 10900
9th 13200
10th 15100
11th 17400
12th 19900 (calculated)
13th 22300
14th 24300
15th 26100
16th 28400
17th 30600
18th 33000
19th 35400
20th 38400
21st 40600
Ionisation energies of einsteinium
Ionisation energies of einsteinium.
(追記) (追記ここまで)

Effective Nuclear Charges

The following are "Clementi-Raimondi" effective nuclear charges, Zeff. Follow the hyperlinks for more details and for graphs in various formats.

Effective nuclear charges for einsteinium
1s (no data)
2s (no data) 2p (no data)
3s (no data) 3p (no data) 3d (no data)
4s (no data) 4p (no data) 4d (no data) 4f (no data)
5s (no data) 5p (no data) 5d (no data)
6s (no data) 6p (no data)
7s

References

These effective nuclear charges, Zeff, are adapted from the following references:

  1. E. Clementi and D.L.Raimondi, J. Chem. Phys. 1963, 38, 2686.
  2. E. Clementi, D.L.Raimondi, and W.P. Reinhardt, J. Chem. Phys. 1967, 47, 1300.

Electron binding energies

Electron binding energies for einsteinium. All values of electron binding energies are given in eV. The binding energies are quoted relative to the vacuum level for rare gases and H2, N2, O2, F2, and Cl2 molecules; relative to the Fermi level for metals; and relative to the top of the valence band for semiconductors.
Label Orbital eV [literature reference]

Notes

I am grateful to Gwyn Williams (Jefferson Laboratory, Virginia, USA) who provided the electron binding energy data. The data are adapted from references 1-3. They are tabulated elsewhere on the WWW (reference 4) and in paper form (reference 5).

References

  1. J. A. Bearden and A. F. Burr, "Reevaluation of X-Ray Atomic Energy Levels," Rev. Mod. Phys., 1967, 39, 125.
  2. M. Cardona and L. Ley, Eds., Photoemission in Solids I: General Principles (Springer-Verlag, Berlin) with additional corrections, 1978.
  3. Gwyn Williams WWW table of values
  4. D.R. Lide, (Ed.) in Chemical Rubber Company handbook of chemistry and physics , CRC Press, Boca Raton, Florida, USA, 81st edition, 2000.
  5. J. C. Fuggle and N. Mårtensson, "Core-Level Binding Energies in Metals," J. Electron Spectrosc. Relat. Phenom., 1980, 21, 275.

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