Ruthenium hexafluoride
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- InChI=1/6FH.2Ru/h6*1H;;/q;;;;;;+6/p-6Key: NHWBVRAPBLSUQQ-UHFFFAOYSA-H
- F[Ru](F)(F)(F)(F)F
Ruthenium hexafluoride, also ruthenium(VI) fluoride (RuF6), is a compound of ruthenium and fluorine and one of the seventeen known binary hexafluorides.
History and synthesis
[edit ]Ruthenium hexafluoride was discovered by American radiochemists in 1961, soon after the discovery of technetium hexafluoride.[3] It is made by a direct reaction of ruthenium metal in a gas stream of fluorine and argon at 400–450 °C. The yields of this reaction are less than 10%.[4]
- Ru + 3 F
2 → RuF
6
Description
[edit ]Ruthenium hexafluoride is a dark brown crystalline solid that melts at 54 °C.[1] The solid structure measured at −140 °C is orthorhombic space group Pnma. Lattice parameters are a = 9.313 Å, b = 8.484 Å, and c = 4.910 Å. There are four formula units (in this case, discrete molecules) per unit cell, giving a density of 3.68 g·cm−3.[4]
The RuF6 molecule itself (the form important for the liquid or gas phase) has octahedral molecular geometry, which has point group (Oh ). The Ru–F bond length is 1.818 Å.[4]
References
[edit ]- ^ a b c CRC Handbook of Chemistry and Physics , 90th Edition, CRC Press, Boca Raton, Florida, 2009, ISBN 978-1-4200-9084-0, Section 4, Physical Constants of Inorganic Compounds, p. 4-85.
- ^ Haynes, William M (2014年06月04日). CRC Handbook of Chemistry and Physics, 95th Edition. CRC Press. ISBN 9781482208689.
- ^ Claassen, Howard H.; Selig, Henry; Malm, John G.; Chernick, Cedric L.; Weinstock, Bernard (1961). "RUTHENIUM HEXAFLUORIDE". Journal of the American Chemical Society. 83 (10): 2390–2391. doi:10.1021/ja01471a039. ISSN 0002-7863.
- ^ a b c T. Drews, J. Supeł, A. Hagenbach, K. Seppelt: "Solid State Molecular Structures of Transition Metal Hexafluorides", in: Inorganic Chemistry , 2006, 45 (9), S. 3782–3788; doi:10.1021/ic052029f; PMID 16634614.
Further reading
[edit ]- Gmelins Handbuch der anorganischen Chemie , System Nr. 63, Ruthenium, Supplement, pp. 266–268.
External links
[edit ]- Media related to Ruthenium hexafluoride at Wikimedia Commons
- Ruthenium hexafluoride at webelements.com.
