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Pentacarbonylhydridorhenium

From Wikipedia, the free encyclopedia
Pentacarbonylhydridorhenium
Names
IUPAC name
pentacarbonylhydridorhenium
Identifiers
3D model (JSmol)
  • InChI=1S/5CO.Re.H/c5*1-2;; checkY
    Key: CNPMTNYPOCHKNC-UHFFFAOYSA-N checkY
  • InChI=1/5CO.Re.H/c5*1-2;;/rC5HO5Re/c6-1-11(2-7,3-8,4-9)5-10/h11H
    Key: CNPMTNYPOCHKNC-AUQHHBNCAA
  • C(#O)[ReH](C#O)(C#O)(C#O)C#O
Properties
ReH(CO)5
Molar mass 327.265 g/mol
Appearance Colorless liquid
Density 2.30 g/mL, liquid
Melting point 12.5 °C (54.5 °F; 285.6 K)
Boiling point 100 °C (212 °F; 373 K) (decomposes)
Insoluble
Hazards
Occupational safety and health (OHS/OSH):
Main hazards
 Flammable
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
checkY verify  (what is checkY☒N ?)
Chemical compound

Pentacarbonylhydridorhenium is a chemical compound with the formula ReH(CO)5. This colorless liquid is a weak acid and represents one of the most important derivatives of dirhenium decacarbonyl (Re2(CO)10). It is synthesized by treating a methanolic solution of bromopentacarbonylrhenium(I) (Re(CO)5Br) with zinc and acetic acid (HOAc).[1]

Re(CO)5Br + Zn + HOAc → ReH(CO)5 + ZnBrOAc

It is moderately sensitive to light: samples turn yellow due to the formation of the metal cluster Re3H(CO)14

3 Re(CO)5H → Re3H(CO)14 + H2 + CO

At 100 °C, it decomposes to Re2(CO)10:[1]

2 Re(CO)5H → H2 + Re2(CO)10

References

[edit ]
  1. ^ a b Michael A. Urbancic, John R. Shapley (1990). "Pentacarbonylhydridorhenium". Inorganic Syntheses . 28: 165–8. doi:10.1002/9780470132593.ch43. ISBN 9780470132593.
Rhenium(0)
Organorhenium(0)
Rhenium(I)
Organorhenium(I)
Rhenium(II)
Rhenium(III)
Rhenium(IV)
Rhenium(V)
Rhenium(VI)
Rhenium(VII)
Perrhenates
Organorhenium(VII)
Metal carbonyl complexes
H2CO He
Li Be2(CO)4 H3BCO C(CO)2
(C=C)(CO)2
(HC=CH)CO NCO− OCO F2CO
H(CO)F
(FCO)2 Ne
Na Mg(O3)2(CO)2 Al Si PCO− SCO Cl2CO
(ClCO)2 Ar
K Ca(CO)8 Sc(CO)8− Ti(CO)7
Ti(CO)62-
Cp2Ti(CO)2 V(CO)6
C5H5V(CO)4
V(CO)6− Cr(CO)6
C6H6Cr(CO)3 Mn2(CO)10
Mn(CO)5− Co2(CO)8
Co4(CO)12
Co(CO)4−
HC(Co(CO)3)3 Ni(CO)4 (Cu(CO)Cl)n Zn Ga Ge As SeCO Br2CO Kr
Rb Sr(CO)8 Y(CO)8− Zr Nb Mo(CO)6
C7H8Mo(CO)3 Tc2(CO)10
Tc(CO)5− Ru(CO)5
Ru3(CO)12
Ru(CO)42− Rh4(CO)12
Rh6(CO)16
Rh2Cl2(CO)2 Pd(CO)4 [Ag(CO)][B(OTeF5)4] Cd In Sn Sb Te I Xe
Cs Ba(CO)8 * Lu Hf Ta W(CO)6
(C5H5)2W2(CO)6 Re2(CO)10
Re(CO)5− Os(CO)5
Os3(CO)12
Os(CO)42−
Os3(CO)102- Ir4(CO)12 Pt Au Hg Tl Pb Bi Po At Rn
Fr Ra ** Lr Rf Db Sg(CO)6 Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
 
* La(CO)8− Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb
** Ac Th Pa U Np Pu Am Cm Bk Cf Es Fm Md No

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