Zirconium monophosphide
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(Redirected from Zirconium phosphide)
"Zirconium phosphide" redirects here. For the diphosphide, see Zirconium diphosphide.
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| IUPAC name
Phosphinidinzirconium
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| Identifiers | |
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3D model (JSmol)
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CompTox Dashboard (EPA)
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| Properties | |
| PZr | |
| Molar mass | 122.198 g·mol−1 |
| Appearance | solid |
| Hazards | |
| GHS labelling: | |
| GHS09: Environmental hazard GHS05: Corrosive GHS06: Toxic | |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Chemical compound
Zirconium monophosphide is a binary inorganic compound of zirconium metal and phosphorus with the chemical formula ZrP.[1] [2] [3]
Preparation
[edit ]Zirconium monophosphide can be prepared from direct reaction of zirconium powders with red phosphorus:[4]
- 4 Zr + P4 → 4 ZrP
Physical properties
[edit ]The α-form of zirconium monophosphide has a NaCl crystal structure.[5] The β-form structure is hexagonal. The α-form is a superconductor if cooled below 5K.[6]
References
[edit ]- ^ "Zirconium Phosphide". American Elements . Retrieved 7 March 2024.
- ^ Irani, K. S.; Gingerich, K. A. (1 October 1963). "Structural transformation of zirconium phosphide". Journal of Physics and Chemistry of Solids . 24 (10): 1153–1158. doi:10.1016/0022-3697(63)90231-2. ISSN 0022-3697 . Retrieved 7 March 2024.
- ^ O'Bannon, Loran (6 December 2012). Dictionary of Ceramic Science and Engineering. Springer Science & Business Media. p. 283. ISBN 978-1-4613-2655-7 . Retrieved 7 March 2024.
- ^ Li, Zhen; Chen, Ning; Wang, Jigang; Li, Peishen; Guo, Ming; Wang, Qiang; Li, Chunhong; Wang, Changzheng; Guo, Tao; Chen, Shaowei (12 October 2017). "Efficient reduction of nitric oxide using zirconium phosphide powders synthesized by elemental combination method" (PDF). Scientific Reports . 7 (1): 13044. doi:10.1038/s41598-017-13616-5. PMC 5638856 . PMID 29026175.
- ^ Swanson, Howard Eugene (1962). Standard X-ray Diffraction Powder Patterns: Data for 46 substances. National Bureau of Standards. p. 75. Retrieved 7 March 2024.
- ^ Macintyre, Jane E. (23 July 1992). Dictionary of Inorganic Compounds. CRC Press. p. 3769. ISBN 978-0-412-30120-9 . Retrieved 7 March 2024.