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Zinc titanate

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Zinc titanate
Names
Other names
Zinc titanium oxide
Identifiers
3D model (JSmol)
ChemSpider
EC Number
  • 234-850-0
UNII
  • InChI=1S/3O.Ti.Zn/q;2*-1;;+2
    Key: DJSKLKQRHSKRDZ-UHFFFAOYSA-N
  • [O-][Ti](=O)[O-].[Zn+2]
Properties
ZnTiO3
Molar mass 161.24 g/mol
Appearance White powder
Insoluble
Hazards
GHS labelling:
GHS07: Exclamation mark
Warning
H302, H331
P260, P261
NFPA 704 (fire diamond)
Flash point None
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Chemical compound

Zinc titanate, also known as zinc titanium oxide, is an inorganic compound existing in three major forms: ZnTiO3 (ZnO-TiO2), Zn2TiO4 (2ZnO-TiO2) and Zn2Ti3O8 (2ZnO-3TiO2). It is used as a regenerable catalyst, a pigment and a sorbent of sulfur compounds at elevated temperatures.[1] It is a white powder that is insoluble in water.

Synthesis and properties

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The ZnTiO3, Zn2TiO4 and Zn2Ti3O8 forms crystallize in hexagonal, cubic (inverse spinel) and cubic structures, respectively. They can be produced by heating a mixture of ZnO and TiO2 powders or processing it with a ball mill.[1] Zn2Ti3O8 forms at lowest temperatures, followed by ZnTiO3 and then Zn2TiO4; the last phase dominates at temperatures above 1000 °C.[2]

References

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  1. ^ a b Klaus D. Sattler (1 May 2010). Nanotubes and Nanowires. CRC Press. pp. 13–. ISBN 978-1-4200-7542-7 . Retrieved 10 March 2012.
  2. ^ Aysel T. Atimtay; Douglas P. Harrison (1998). Desulfurization of hot coal gas. Springer. pp. 300–. ISBN 978-3-540-64726-3 . Retrieved 10 March 2012.
Titanium(II)
Organotitanium(II) compounds
Titanium(III)
Organotitanium(III) compounds
Titanium(IV)
Titanate compounds
Organotitanium(IV) compounds
Titanate salts
H He
Li2TiO3
Li4Ti5O12 Be B C N O F Ne
Na2TiO3 Mg Al Si P S Cl Ar
K CaTiO3 Sc Ti V Cr MnTiO3 Fe Co NiTiO3 Cu ZnTiO3
Zn2TiO4
Zn2Ti3O8 Ga Ge As Se Br Kr
Rb SrTiO3 Y Zr Nb Mo Tc Ru Rh Pd Ag Cd In Sn Sb Te I Xe
Cs2TiO3 BaTiO3
Ba2TiO4 * Lu Hf Ta W Re Os Ir Pt Au Hg Tl PbTiO3 Bi12TiO20
Bi4Ti3O12
Bi2Ti2O7 Po At Rn
Fr Ra ** Lr Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
 
* La Ce Pr Nd Pm Sm EuTiO3 Gd Tb Dy2Ti2O7 Ho2Ti2O7 Er Tm Yb
** Ac Th Pa U Np Pu Am Cm Bk Cf Es Fm Md No


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