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Ytterbium(III) iodate

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Ytterbium(III) iodate
Identifiers
3D model (JSmol)
  • InChI=1S/3HIO3.Yb/c3*2-1(3)4;/h3*(H,2,3,4);/q;;;+3/p-3
    Key: LLMQNIXRCPRHGZ-UHFFFAOYSA-K
  • [Yb+3].O=I(=O)[O-].O=I(=O)[O-].O=I(=O)[O-]
Properties
Yb(IO3)3
Molar mass 697.75
Appearance colourless crystals (dihydrate)[1]
Density 5.067 g·cm−3 (dihydrate)[2]
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Chemical compound

Ytterbium(III) iodate is an inorganic compound with the chemical formula Yb(IO3)3. Its dihydrate can be prepared by reacting ytterbium sulfate and iodic acid in water at 200 °C.[1] It crystallizes in the P21/c space group, with unit cell parameters a=8.685, b=6.066, c=16.687 Å, β=115.01°.[3]

References

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  1. ^ a b Phanon, D.; Gautier-Luneau, I. (Apr 2006). "Crystal structure of ytterbium triiodate dihydrate, Yb[IO3]3 · 2H2O". Zeitschrift für Kristallographie - New Crystal Structures. 221 (1–4): 245–246. doi:10.1524/ncrs.2006.221.14.245 . ISSN 2197-4578.
  2. ^ Douglas, Paul; Hector, Andrew L.; Levason, William; Light, Mark E.; Matthews, Melissa L.; Webster, Michael (Mar 2004). "Hydrothermal Synthesis of Rare Earth Iodates from the Corresponding Periodates: II 1) . Synthesis and Structures of Ln(IO 3 ) 3 (Ln = Pr, Nd, Sm, Eu, Gd, Tb, Ho, Er) and Ln(IO 3 ) 3 · 2H 2 O (Ln = Eu, Gd, Dy, Er, Tm, Yb)". Zeitschrift für anorganische und allgemeine Chemie. 630 (3): 479–483. doi:10.1002/zaac.200300377. ISSN 0044-2313.
  3. ^ Abrahams, S.C.; Bernstein, J.L.; Nassau, K. (Jan 1976). "Transition metal iodates. VII. Crystallographic and nonlinear optic survey of the 4f-iodates". Journal of Solid State Chemistry. 16 (1–2): 173–184. Bibcode:1976JSSCh..16..173A. doi:10.1016/0022-4596(76)90020-7.

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