Peroxynitric acid
From Wikipedia, the free encyclopedia
Peroxynitric acid
Names
Preferred IUPAC name
Systematic IUPAC name
Identifiers
ChemSpider
Properties
HNO4
Molar mass
79.01224 g/mol
Conjugate base
Peroxynitrate
Related compounds
Hydroxy nitrate
- 26404-66-0 ☒N
3D model (JSmol)
- 58833 checkY
PubChem CID
CompTox Dashboard (EPA)
- [N+](=O)([O-])OO
Related compounds
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Chemical compound
Peroxynitric acid or peroxonitric acid is a chemical compound with the formula HNO
4. It is an oxyacid of nitrogen, after peroxynitrous acid.
Preparation
[edit ]Peroxynitrate, the conjugate base of peroxynitric acid, is formed rapidly during decomposition of peroxynitrite in neutral conditions.[4]
Atmospheric chemistry
[edit ]Peroxynitric acid is formed in the atmosphere, although it is unstable, it is important as a reservoir for NO2 through the reversible radical reaction:[5]
- HO
2NO
2 ⇌ HO•
2 + NO•
2
References
[edit ]- ^ "Peroxynitric Acid - Compound Summary".
- ^ "peroxynitric acid". PubChem. Retrieved 9 December 2012.
- ^ "125239-87-4". ChemIndex. Retrieved 9 December 2012.
- ^ Miyamoto, S; Ronsein, GE; Corrêa, TC; Martinez, GR; Medeiros, MH; Di Mascio, P (2009). "Direct evidence of singlet molecular oxygen generation from peroxynitrate, a decomposition product of peroxynitrite". Dalton Trans (29): 5720–9. doi:10.1039/b905560f. PMID 20449086.
- ^ Finlayson-Pitts, Barbara J.; Pitts, James N. (2000), Chemistry of the Upper and Lower Atmosphere, Elsevier, p. 100, doi:10.1016/b978-012257060-5/50000-9 , ISBN 978-0-12-257060-5 , retrieved 2020年09月24日
