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Hydrozincite

From Wikipedia, the free encyclopedia
White carbonate mineral
"Marionite" redirects here. For the religious group, see Maronite. For people called Marionites, see Marion (disambiguation) § places.
Hydrozincite
General
CategoryCarbonate mineral
Formula
(repeating unit)
Zn5(CO3)2(OH)6
IMA symbol Hznc[1]
Strunz classification 5.BA.15
Crystal system Monoclinic
Crystal class Prismatic (2/m)
(same H-M symbol)
Space group C2/m
Unit cell a = 13.58 Å, b = 6.28 Å,
c = 5.41 Å; β = 95.51°, Z = 2
Identification
ColorWhite to grey, stained pale pink, or pale yellow or brown; colourless in transmitted light.
Crystal habit Lathlike or bladed crystals uncommon, in fibrous, stalactitic, reniform, pisolitic aggregates; also earthy, chalky, massive
Twinning Contact twinning on {100}
Cleavage Perfect on {100}
Fracture Irregular/uneven
Tenacity Very brittle
Mohs scale hardness2–2+12
Luster Silky, pearly, dull, earthy
Streak White
Diaphaneity Transparent, translucent
Specific gravity 3.5–4
Optical propertiesBiaxial (−)
Refractive index nα = 1.630 nβ = 1.642 nγ = 1.750
Birefringence δ = 0.120
2V angle Measured: 40°, calculated: 40°
Dispersion relatively strong
Ultraviolet fluorescence Fluoresces pale blue to lilac under UV
Solubility Readily soluble in acids.
References[2] [3] [4]

Hydrozincite, also known as zinc bloom or marionite, is a white carbonate mineral consisting of Zn 5(CO3)2(OH)6. It is usually found in massive rather than crystalline form.

It occurs as an oxidation product of zinc ores and as post mine incrustations. It occurs associated with smithsonite, hemimorphite, willemite, cerussite, aurichalcite, calcite and limonite.[2]

It was first described in 1853 for an occurrence in Bad Bleiberg, Carinthia, Austria and named for its chemical content.[3]

References

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