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Fluomine

From Wikipedia, the free encyclopedia
Fluomine
Names
Other names
  • Fluomine dust
  • Cobalt(II), N,N'-ethylenebis-(3-fluorosalicyclideneiminato)-
  • Cobalt, bis(3-fluorosalicylaldehyde)ethylenediimine-
Identifiers
3D model (JSmol)
ECHA InfoCard 100.057.672 Edit this at Wikidata
EC Number
  • 263-458-2
  • InChI=1S/C16H14F2N2O2.Co/c17-13-3-1-5-15(21)11(13)9-19-7-8-20-10-12-14(18)4-2-6-16(12)22;/h1-6,9-10,21-22H,7-8H2;/q;+2/p-2/b19-9+,20-10+;
    Key: VUNNDCACJFYYFK-HCURTGQUSA-L
  • c12c(cccc1[O-][Co+2]13[N](=C2)CC[N]1=Cc1c(cccc1[O-]3)F)F
Properties
C16H12CoF2N2O2
Molar mass 361.214 g·mol−1
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Chemical compound


Fluomine is a chemical compound containing a cobalt chelate. It has the ability to form a complex with molecular oxygen (O2) and then release it upon heating.[1] Because of this ability to reversibly sorb and desorb oxygen, it has been used in high-altitude aircraft oxygen-generating systems.[2] [3]

The toxicity of fluomine has been studied[1] [4] and it is classified by the Emergency Planning and Community Right-to-Know Act as an extremely hazardous substance.[5]

References

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  1. ^ a b Kinkead, E.R.; Haun, C.C.; Bowers, R.S.; Vernot, E.H.; Mac Ewen, J.D.; Amster, R.L. (1981). "The mammalian toxicity of fluomine dust". American Industrial Hygiene Association Journal. 42 (9): 675–680. doi:10.1080/15298668191420503. PMID 7293930.
  2. ^ Manatt, S. A. (1981). "Onboard oxygen generation systems". Aviation, Space, and Environmental Medicine. 52 (11 Pt 1): 645–53. PMID 7305791.
  3. ^ "Breathing Oxygen: Purity of Oxygen Generated By a Fulomine-Based System" (PDF). USAF School of Aerospace Medicine, Aerospace Medical Division (AFSC). September 1976. Archived (PDF) from the original on June 1, 2022. Retrieved March 10, 2019.
  4. ^ Kinkead, E.R.; Haun, C.C.; Bowers, R.S.; Vernot, E.H.; MacEwen, J.D.; Amster, R.L. (1982). "Six month inhalation toxicity of fluomine dust". American Industrial Hygiene Association Journal. 43 (1): 66–71. doi:10.1080/15298668291409361. PMID 7055087.
  5. ^ 40 C.F.R.: Appendix A to Part 355—The List of Extremely Hazardous Substances and Their Threshold Planning Quantities (PDF) (July 1, 2008 ed.), Government Printing Office, archived from the original (PDF) on 2012年02月25日, retrieved March 8, 2009

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