Dimagnesium phosphate

This article is about Dimagnesium phosphate. For other uses, see magnesium phosphate.

Dimagnesium phosphate
Names

Other names Magnesium hydrogen phosphate; Magnesium phosphate dibasic
Identifiers
CAS Number	7757-86-0 ^checkY 7782-75-4 (trihydrate)^checkY
3D model (JSmol)	Interactive image
ChemSpider	110477 ^☒N
ECHA InfoCard	100.028.930 Edit this at Wikidata
EC Number	231-823-5
E number	E343(ii) (antioxidants, ...)
PubChem CID	123955
UNII	A1Y870209Z ^checkY HF539G9L3Q (trihydrate)^checkY
CompTox Dashboard (EPA)	DTXSID00872522 Edit this at Wikidata
InChI InChI=1S/Mg.H3O4P/c;1-5(2,3)4/h;(H3,1,2,3,4)/q+2;/p-2^☒N Key: MHJAJDCZWVHCPF-UHFFFAOYSA-L^☒N
SMILES O=P([O-])(O)[O-].[Mg+2]
Properties
Chemical formula	HMgO₄P
Molar mass	120.283 g·mol⁻¹
Density	2.13 g/cm3 trihydrate
Hazards
NFPA 704 (fire diamond)	[画像:NFPA 704 four-colored diamond] Health 0: Exposure under fire conditions would offer no hazard beyond that of ordinary combustible material. E.g. sodium chloride Flammability 0: Will not burn. E.g. water Instability 0: Normally stable, even under fire exposure conditions, and is not reactive with water. E.g. liquid nitrogen Special hazards (white): no code 0 0 0
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). ☒N verify (what is ^checkY☒N ?) Infobox references

Chemical compound

Dimagnesium phosphate is a compound with formula MgHPO₄. It is a Mg²⁺ salt of monohydrogen phosphate. The trihydrate is well known, occurring as a mineral.^[1]

It can be formed by reaction of stoichiometric quantities of magnesium oxide with phosphoric acid.

MgO + H₃PO₄ → MgHPO₄ + H₂O

Dissolving monomagnesium phosphate in water, forms phosphoric acid and depositing a solid precipitate of dimagnesium phosphate trihydrate:

Mg(H₂PO₄)₂ + 3 H₂O → Mg(HPO₄)^.3H₂O + H₃PO₄

The compound is used as a nutritional supplement, especially for infants and athletes. Its E number is E343.^[2]

References

^ Klaus Schrödter; Gerhard Bettermann; Thomas Staffel; Friedrich Wahl; Thomas Klein; Thomas Hofmann (2008). "Phosphoric Acid and Phosphates". Ullmann's Encyclopedia of Industrial Chemistry. Ullmann’s Encyclopedia of Industrial Chemistry. Weinheim: Wiley-VCH. doi:10.1002/14356007.a19_465.pub3. ISBN 978-3527306732. S2CID 94458523.
^ relevant part of the German "Zusatzstoff-Zulassungsverordnung Archived 2012年05月18日 at the Wayback Machine", the official German implementation of the respective regulation of the European Union

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