2-Methoxypropene
From Wikipedia, the free encyclopedia
Preferred IUPAC name
2-Methoxyprop-1-ene
Other names
Methyl isopropenyl ether
Isopropenyl methyl ether
Isopropenyl methyl ether
3D model (JSmol)
- InChI=1S/C4H8O/c1-4(2)5-3/h1H2,2-3H3Key:YOWQWFMSQCOSBA-UHFFFAOYSA-N
- InChI=1/C4H8O/c1-4(2)5-3/h1H2,2-3H3Key:YOWQWFMSQCOSBA-UHFFFAOYAD
- CC(=C)OC
Molar mass
72.107g·mol−1
Appearance
Colorless liquid[1]
Boiling point
34 to 36°C (93 to 97°F; 307 to 309K)[2]
Except where otherwise noted, data are given for materials in their standard state (at 25°C [77°F], 100kPa).
Chemical compound
2-Methoxypropene is an ether with the chemical formula C4H8O. It is a reagent used in organic synthesis to introduce a protecting group for alcohols,[1] and the conversion diols to the acetonide group.[3]
2-Methoxypropene can be prepared by the elimination of methanol from dimethoxypropane,[4] or by the addition of methanol to propyne or allene.[5]
References
[edit ]- 1 2 Whitaker, K. Sinclair; Whitaker, D. Todd (2001). "2-Methoxypropene". Encyclopedia of Reagents for Organic Synthesis. doi:10.1002/047084289X.rm124. ISBN 0471936235.
- 1 2 2-Methoxypropene at Sigma-Aldrich
- ↑ Theodora W. Greene; Peter G. M. Wuts. Protective Groups in Organic Synthesis (3rd ed.). pp. 207–215.
- ↑ Newman, Melvin S.; Vander Zwan, Michael C. (1973). "Improved synthesis of 2-methoxypropene". The Journal of Organic Chemistry. 38 (16): 2910. doi:10.1021/jo00956a040.
- ↑ Agré, B. A.; Taber, A. M.; Beregovykh, V. V.; Klebanova, F. D.; Nekrasov, N. V.; Sobolev, O. B.; Kalechits, I. V. (1983). "Kinetics of the catalytic synthesis of 2-methoxypropene". Pharmaceutical Chemistry Journal. 17 (3): 221. doi:10.1007/BF00765172. S2CID 22506880.