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Optically Active Polysilanes. Ten Years of Progress and New Polymer Twist for Nanoscience and Nanotechnology

Polymer Journal volume 35, pages 297–344 (2003) Cite this article

Abstract

In the family of optically active synthetic polymers, optically active polysilanes, which comprise a helical main chain of silicon-silicon single bonds and chiral and/or achiral side groups, exhibit unique absorption, circular dichroism, and fluorescence spectra around 300–400 nm due to σ-conjugation. Since the first brief report of optically active polysilane synthesis in 1992, the field has now widened to include various homo- and copolymers of optically active poly(dialkylsilane)s, poly(dialkoxysilane)s, poly[alkyl(aryl)silane]s, and poly(diarylsilane)s. This review comprehensively covers work on (i) the relationship between side chain structure, (ii) local structure-global shape relationship, (iii) (chir)optical properties, (iv) (semi)quantitative population analysis of right- and left-handed helices based on Kuhn’s dissymmetry ratio, (v) several helical cooperativity effects, (vi) molecular imaging, (vii) inversion of screw-sense, (viii) chiroptical switch and memory, (ix) transfer and amplification of molecular chirality to aggregates, (x) cholesteric liquid crystallinity, (xi) helical supramolecular structures, and (xii) latent helicity, as consequences of side group internal interactions and other external stimuli. Such knowledge and understanding may stimulate optically active polymer research in the realm of nanomaterial science and nanotechnology at the sub-nm level as well as traditional polymer science, and may advance these polymers to new functional nanomaterials and thence to the realization of nanodevices in the future.

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Authors and Affiliations

  1. CREST-JST,

    Michiya Fujiki, Julian Robert Koe, Takahiro Sato, Akio Teramoto & Junji Watanabe

  2. Advanced Polymer Science Laboratory, Graduate School of Materials Science, Nara Institute of Science and Technology (NAIST),

    Michiya Fujiki

  3. Department of Chemistry, International Christian University,

    Julian Robert Koe

  4. Department of Biological and Chemical Engineering, Gunma University,

    Ken Terao

  5. Department of Macromolecular Science, Osaka University,

    Takahiro Sato

  6. Research Organization of Science and Engineering, Ritsumeikan University,

    Akio Teramoto

  7. Department of Organic and Polymeric Materials, Tokyo Institute of Technology,

    Junji Watanabe

Authors
  1. Michiya Fujiki
  2. Julian Robert Koe
  3. Ken Terao
  4. Takahiro Sato
  5. Akio Teramoto
  6. Junji Watanabe

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Fujiki, M., Koe, J., Terao, K. et al. Optically Active Polysilanes. Ten Years of Progress and New Polymer Twist for Nanoscience and Nanotechnology. Polym J 35, 297–344 (2003). https://doi.org/10.1295/polymj.35.297

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