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Researcher Information

last modified:2025年04月07日

Associate Professor Yuji Kikukawa

Faculty, Affiliation

Faculty of Chemistry, Institute of Science and Engineering

College and School Educational Field

Division of Material Chemistry, Graduate School of Natural Science and Technology
Division of Material Chemistry, Graduate School of Natural Science and Technology
School of Chemistry, College of Science and Engineering

Laboratory

Inorganic Lab

Academic Background

【Academic background(Doctoral/Master's Degree)】
The University of Tokyo Doctor School of Engineering Applied Chemistry 201103 Completed
The University of Tokyo Master School of Engineering Applied Chemistry 200803 Completed
【Academic background(Bachelor's Degree)】
The University of Tokyo Applied Chemistry 200603

Career

Japan Science and Technology Agency(2016年10月01日-2020年03月31日)

Year & Month of Birth

1982/05

Academic Society


Catalysis Society of Japan
The Chemical Society of Japan

Award








しろまるCSJ Presentation Award(2012/03)
しろまるInoue Research Award for Young Scientists(2013/12)

Specialities

Inorganic chemistry、Catalyst/Resource chemical process

Speciality Keywords

metal-oxide molecules, catalyst, functional materials

Research Themes

Books

Papers

  • Synthesis and oxidation catalysis of a difluoride-incorporated polyoxovanadate and isolation of active vanadium alkylperoxo species Yuji Kikukawa, Yui Sakamoto, Hikari Hirasawa, Yushi Kurimoto, Hiroya Iwai, Yoshihito Hayashi Catalysis Science & Technology 2022年01月05日
  • Ultra-High Proton Conduction via Extended Hydrogen-Bonding Network in a Preyssler-type Polyoxometalate-Based Framework Functionalized with Lanthanide Ion Tsukasa Iwano, Kota Shitamatsu, Naoki Ogiwara, Masanari Okuno, Yuji Kikukawa, Satory Ikemoto, Sora Shirai, Satoshi Muratsugu, Paul Waddell, John, R. Errington, Masahiro Sadakane, Sayaka Uchida ACS Applied Materials & Interfaces 13 19138 2021年04月19日
  • Synthesis of Cyanooxovanadate and Cyanosilylation of Ketones Yuji Kikukawa, Hiroko Kawabata, Yoshihito Hayashi RSC Advances 11 31688 2021年09月27日
  • Incorporating highly-basic polyoxometalate anions comprising Nb or Ta into nanoscale reaction fields of porous ionic crystals Zhewei Weng, Naoki Ogiwara, Takashi Kitao, Takashi, Yuji Kikukawa, Yu Gao, Li-Kai Yan, Sayaka Uchida, Nanoscale 13 18451 2021年10月01日
  • Isostructural Mesoporous Ionic Crystals as a Tunable Platform for Acid Catalysis Yuto Shimoyama, Zhewei Weng, Naoki Ogiwara, Takashi Kitao, Yuji Kikukawa, Sayaka Uchida Dalton Transactions 49 10328 2020年06月05日


  • Induced-Fitting and Polarization of Bromine Molecule in an Electrophilic Inorganic Molecular Cavity and Its Bromination Reactivity Yuji Kikukawa, Kensuke Seto, Daiki Watanabe, Hiromasa Kitajima, Misaki Katayama, Shohei Yamashita, Yasuhiro Inada, Yoshihito Hayashi Angewandte Chemie, International Edition 59 14399 2020年06月08日
  • Isolation of a Nitromethane Anion in the Calix-Shaped Inorganic Cage Yuji Kikukawa, Hiromasa Kitajima, Sho Kuwajima, Yoshihito Hayashi Molecules 25 5670 2020年12月01日
  • Redox active mixed-valence hexamanganese double-cubane complexes supported by tetravanadates Tatsuya Maruyama, Akimi Namekata, Hiroshi Sakiyama, Yuji Kikukawa, Yoshihito Hayashi New Journal of Chemistry 43 17703 2019年07月23日
  • Evaluation of Chemo- and Shape-Selective Association of a Bowl-Type Dodecavanadate Cage with an Electron-Rich Group Yuji Kikukawa, Hiromasa Kitajima, Yoshihito Hayashi Dalton Transactions 48 7138 2019年04月04日
  • Solid State Umbrella-type Inversion of a VO5 Square Pyramidal Unit in a Bowl-type Dodecavanadate Induced by Insertion and Elimination of a Guest Molecule Yuji Kikukawa, Kensuke Seto, Sayaka Uchida, Sho Kuwajima, Yoshihito Hayashi Angewandte Chemie, International Edition 57 16051-16055 2018年10月15日
  • Synthesis and structural characterization of tube type tetradecavanadates Sho Kuwajima, Yuta Arai, Hiromasa Kitajima, Yuji Kikukawa, Yoshihito Hayashi Acta Crystallographica Section C 74 1295-1299 2018年11月01日
  • Synthesis and Characterization of Yttrium-containing Sandwich-, Ring-, and Cage-type Polyoxovanadates Tatsuya Maruyama, Hiroko Kawabata, Yuji Kikukawa, Yoshihito Hayashi European Journal of Inorganic Chemistry 2019 3-4 529-533 2018年08月09日
  • Synthesis and Characterization of a Palladium-Supported Fluoride-Incorporated Dodecavanadate Miftahul Khair, Yuji Kikukawa, Yoshihito Hayashi Chemistry Letters 46 1406-1408 2017年07月12日
  • A Highly-flexible Cyclic-decavanadate Ligand for Interconversion of Dinuclear- and Trinuclear-cobalt(II) and Manganese(II) Cores Tatsuya Maruyama, Yuji Kikukawa, Hiroshi Sakiyama, Misaki Katayama, Yasuhiro Inada, Yoshihito Hayashi RSC Advances 7 37666-37674 2017年08月01日
  • Water- and Temperature-Triggered Reversible Structural Transformation of Tetranuclear Cobalt(II) Cores Sandwiched by Polyoxometalates Yosuke Kuriyama, Yuji Kikukawa, Kosuke Suzuki, Kazuya Yamaguchi, Noritaka Mizuno Chemistry A European Journal 22 3962-3966 2016年02月05日
  • A Bowl-Type Dodecavanadate as a Halide Receptor Sho Kuwajima, Yuka Ikinobu, Daiki Watanabe, Yuji Kikukawa, Yoshihito Hayashi, Atsushi Yagasaki ACS Omega 2 268-275 2017年01月26日
  • Synthesis and Structural Characterization of Trimanganese-Containing Polyoxovanadates with Carboxylate Ligands Tatsuya Maruyama, Yuji Kikukawa, Keisuke Kawamoto, Yoshihito Hayashi European Journal of Inorganic Chemistry 2017 596-599 2017年01月18日
  • Small Molecular Anion Recognition by a Shape-responsive Bowl-Type Dodecavanadate Sho Kuwajima, Yuji Kikukawa, Yoshihito Hayashi Chemistry-An Asian Journal 2017年04月22日
  • Chloride capturing system via proton-induced structure transformation between opened- and closed-forms of dodecavanadates Yoshitaka Inoue, Yuji Kikukawa, Sho Kuwajima, Yoshihito Hayashi Dalton Transaction 45 7563-7569 2016
  • Synthesis and oxidation catalysis of a Ti-substituted phosphotungstate, and identification of the active oxygen species Eri Takahashi, Keigo Kamata, Yuji Kikukawa, Sota Sato, Kosuke Suzuki, Kazuya Yamaguchi, Noritaka Mizuno Catalysis Science & Technology 5 4778-4789 2015
  • Structure Transformation among Deca-, Dodeca- and Tridecavanadates and Their Properties for Thioanisole Oxidation Yuji Kikukawa, Kazuhiro Ogihara, Yoshihito Hayashi Inorganics 3 295-308 2015
  • Layered Assemblies of Dialuminum-Substituted Silicotungstate Trimer and the Reversible Interlayer Cation-Exchange Properties Yuji Kikukawa, Kazuya Yamaguchi, Mitsuhiro Hibino, Noritaka Mizuno Inorganic Chemistry 50 12411-12413 2011
  • Synthesis and characterization of fluoride-incorporated polyoxovanadates Yuji Kikukawa, Taiga Yokoyama, Sanae Kashio, Yoshihito Hayashi Journal of Inorganic Biochemistry 147 221-226 2015
  • Hydrogen Evolution Using the Visible-Light-Induced Metal-to-Polyoxometalate Multiple Electron Transfer Kosuke Suzuki, Fei Tang, Yuji Kikukawa, Kazuya Yamaguchi, Noritaka Mizuno Chemistry Letters 43 1429-1431 2014
  • Visible Light-Induced Photoredox Catalysis of a Tetracerium-Containing Silicotungstate Kosuke Suzuki, Fei Tang, Yuji Kikukawa, Kazuya Yamaguchi, Noritaka Mizuno Angewandte Chemie, International Edition 53 5356-5360 2014
  • Synthesis, Structure Characterization, and Reversible Transformation of a Cobalt Salt of a Dilacunary γ-Keggin Silicotungstate and Sandwich-Type Di- and Tetra-Cobalt-Containing Silicotungstate Dimers Yuji Kikukawa, Kosuke Suzuki, Kazuya Yamaguchi, Noritaka Mizuno Inorganic Chemistry 52 8644-8652 2013
  • A Discrete Octahedrally Shaped [Ag6]4+ Cluster Encapsulated within Silicotungstate Ligands Yuji Kikukawa, Yoshiyuki Kuroda, Kosuke Suzuki, Mitsuhiro Hibino, Kazuya Yamaguchi, Noritaka Mizuno Chemical Communications 49 376-378 2013
  • Strategic Design and Refinement of Lewis Acid-Base Catalysis by Rare-Earth-Metal-Containing Polyoxometalates Kosuke Suzuki, Midori Sugawa, Yuji Kikukawa, Keigo Kamata, Kazuya Yamaguchi, Noritaka Mizuno Inorganic Chemistry 51 6953-6961 2012
  • Cyanosilylation of Carbonyl Compounds with Trimethylsilyl Cyanide by an Yttrium-Pillared Silicotungstate Dimer" Yuji Kikukawa, Kosuke Suzuki, Midori Sugawa, Tomohisa Hirano, Keigo Kamata, Kazuya Yamaguchi, Noritaka Mizuno Angewandte Chemie International Edition 51 3686-3690 2012
  • Three-Dimensional Ordered Arrays of 58 x 58 x 58 A3 Hollow Frameworks in Ionic Crystals of M2Zn2-Substituted Polyoxometallates Kosuke Suzuki, Yuji Kikukawa, Sayaka Uchida, Hiroko Tokoro, Kenta Imoto, Shin-ichi Ohkoshi, Noritaka Mizuno Angewandte Chemie International Edition 51 1597-1601 2012
  • Diamond-Shaped [Ag4]4+ Cluster Encapsulated with Silicotungstate Ligands: Synthesis and the Catalysis for Hydrolytic Oxidation of Silanes Yuji Kikukawa, Yoshiyuki Kuroda, Kazuya Yamaguchi, Noritaka Mizuno Angewandte Chemie International Edition 51 2434-2437 2012
  • Sandwich-Type Zinc-Containing Polyoxometalates with a Hexaprismane core [{Zn2W(O)O3}2]4+: Synthesized by Thermally-Induced Isomerization of a Metastable Polyoxometalate Yuji Kikukawa, Kazuya Yamaguchi, Noritaka Mizuno Inorganic Chemistry 49 8194-8196 2010
  • Zinc(II) Containing γ-Keggin Sandwich-Type Silicotungstate: Synthesis in Organic Media and Oxidation Catalysis Yuji Kikukawa, Kazuya Yamaguchi, Noritaka Mizuno Angewandte Chemie International Edition 49 6096-6100 2010
  • Synthesis of a Dialuminum-Substituted Silicotungstate and the Diastereoselective Cyclization of Citronellal Derivatives Yuji Kikukawa, Syuhei Yamaguchi, Yoshinao Nakagawa, Kazuhiro Uehara, Sayaka Uchida, Kazuya Yamaguchi, Noritaka Mizuno Journal of the American Chemical Society 130 15872-15878 2008
  • Synthesis and Catalysis of Di- and Tetra-nuclear Metal Sandwich-type Silicotungstate [(γ-SiW10O36)2M2(μ-OH)2]10- and [(γ-SiW10O36)2M4(μ4-O)(μ-OH)6]8- (M = Zr or Hf) Yuji Kikukawa, Syuhei Yamaguchi, Kazutaka Tsuchida, Yoshinao Nakagawa, Kauhiro Uehara, Kazuya Yamaguchi, Noritaka Mizuno Journal of the American Chemical Society 130 5472-5478 2008
  • Synthesis and Structural Characterization of a γ-Keggin-Type Dimeric Silicotungstate with a Bis(μ-hydroxo) Dizirconium Core [(γ-SiW10O36)2Zr2(μ-OH)2]10- Syuhei Yamaguchi, Yuji Kikukawa, Kazutaka Tsuchida, Yoshinao Nakagawa, Kazuhiro Uehara, Kazuya Yamaguchi, Noritaka Mizuno Inorganic Chemistry 46 8502-8504 2007
  • Culture and Leukocyte Adhesion Assay of Human Arterial Endothelial Cells in a Glass Microchip Yo Tanaka, Yuji Kikukawa, Kae Sato, Yasiko Sugii, Takehiko Kitamori Analytical Sciences 23 261-266 2007
  • Controlling the symmetry of hexamonodentate 3d-transition metal complexes through symmetry propagation from high-symmetry Ti–Mo and Zr–Mo clusters via hydrogen-bonding interactions Ryoji Mitsuhashi, Yuya Imai, Sugiarto, Hiroshi Sakiyama, Yuji Kikukawa, Yoshihito Hayashi Dalton Transactions 53 16186-16194 2024年09月28日
  • Synthesis of Hollowed Polyoxometalate with a Flipped VO5 Unit by the Elimination of a Centered Organic Molecule Yuji Kikukawa, Mayumi Taga, Yusuke Horikawa, Ryoji Mitsuhashi, Yoshihito Hayashi Inorganic Chemisty 64 344-350 2024年12月21日
  • Tuning Proton Conduction by Staggered Arrays of Polar Preyssler-Type Oxoclusters Tsukasa Iwano, Daiki Akutsu, Horoki Ubukata, Naoki Ogiwara, Yuji Kikukawa, Shuo Wang, Li-Kai Yan, Hiroshi Kageyama, Sayaka Uchida Journal of the American Chemical Society 146 26113–26120 2024年08月09日
  • Synthesis and catalysis of a Co13 disk surrounded by vanadium–oxygen crown Yuji Kikukawa, Isshin Yoshida, Ryoji Mitsuhashi, Masaru Yamane, Yoshihito Hayashi New Journal of Chemistry 48 15307-15312 2024年08月06日
  • Incorporation of Poly(vinyl alcohol) into an Inorganic Framework Based on Eu-Bonded Preyssler-Type Phosphotungstate for Enhanced Proton Conduction Tsukasa Iwano, Sora Shirai, Chaoqi Chen, Zhewei Weng, Yuji Kikukawa, Satoshi Muratsugu, Mizuki Tada, Hiroshi Takatsu, Hiroshi Kageyama, Sayaka Uchida ACS Applied Polymer Materials 6 7926-7931 2024年07月16日
  • Reactivity control of nitrate-incorporating octadecavanadates by changing the oxidation state and metal substitution Isshin Yoshida, Yuji Kikukawa, Ryoji Mitsuhashi, Yoshihito Hayashi Nanoscale 16 10584-10589 2024年05月01日
  • Synthesis of Copper-Substituted Polyoxovanadate and Oxidation of 1-Phenyl Ethanol Isshin Yoshida, Ryoji Mitsuhashi, Yuji Kikukawa, Yoshihito Hayashi Inorganics 12 61 2024年02月19日
  • Mechanistic insights into template-driven polyoxovanadate selfassembly: the role of internal and external templates Stefan Repp, Kim Lara Junginger, Dieter Sorsche, Theresa Zorn,b Ann-Christin Pöppler, Yuji Kikukawa, Yoshihito Hayashi, Carsten Streb Dalton Transactions 2023年02月16日
  • Vanadium-substituted polycationic Al-oxo cluster in a porous ionic crystal exhibiting Lewis acidity Wei Zhou, Naoki Ogiwara, Zhewei Weng, Congcong Zhao, Likai Yan, Yuji Kikukawa, Sayaka Uchida Chemical Communications 58 12548-12551 2022年10月11日
  • Hydrophobic interaction of V12 bowl-type dodecavanadates with alkyl ammonium cations Hiroya Iwai, Tsuyoshi Kasamatsu, Sho Kuwajima, Yuji Kikukawa, Yoshihito Hayashi Polyhedron 224 115985 2022年06月18日
  • Basicity of isostructural porous ionic crystals composed of Nb/Ta-substituted Keggin-type polyoxotungstates Zhewei Weng, Naoki Ogiwara, Daisuke Yokogawa, Takashi Kitao, Yuji Kikukawa, Sayaka Uchida Dalton Transactions 51 8186-8191 2022年04月21日

Conference Presentations

  • Synthesis of Octadecavanadate derivatives and oxidation catalysis (2024年02月21日)
  • Oxidation Catalysis of Octadecavanadonitrate(2023年09月15日)
  • Lid effect of an organic cation on the host-guest property of the vanadate bowl(2022年09月27日)
  • HOST-GUEST CHEMISTRY OF A HALF SPHERICAL DODECAVANADATE AND ITS REACTIVITY(conference:International Conference on Coordination Chemistry)(2022年08月30日)
  • Synthesis and catalysis of a peroxo-vanadium structure on a fluoride-containing polyoxovanadate(conference:The 9th Tokyo Conference on Advanced Catalytic Science and Technology )(2022年07月29日)


  • Synthesis and Oxidation Catalysis of Difluoride-Containing Polyoxovanadates(conference:8th Asian Conference on Coordination Chemistry)(2022年08月08日)
  • Interaction of a Hydrophobic Cation and a Bowl-type Dodecavanadate Complexes(conference:8th Asian Conference on Coordination Chemistry)(2022年08月08日)
  • 中性分子内包ポリオキソバナデートと中空ポリオキソバナデートの合成(2022年03月25日)
  • Synthesis and Catalysis of Nitrate-incorporated polyoxovanadates(2022年02月25日)
  • Synthesis and Oxidation Catalysis of Fluoride-Containing Polyoxovanadates (2021年12月18日)
  • Synthesis and catalysis of Tricyanodioxidevanadate(2021年09月18日)
  • Imposing Trigonal Symmetry in Mononuclear HexaMonodentate Complexes with 3d-Metal Ions(2021年09月17日)
  • Synthesis and Oxidation Catalysis of Molecular Fluorovanadates (conference:Global Catalysis & Applied Chemical Engineering)(2021年08月12日)
  • Anion receptor property of a Dodecavanadate(conference: International Network on Polyoxometalate Science for Advanced Functional Energy Materials )(2021年07月19日)
  • Host-Guest Chemistry of Inorganic Molecular Container and Its Reactivity(conference: The 1st Irkutsk Kanazawa University joint sakigake-symposium in chemistry)(2021年01月27日)
  • Reactivity of a Bromine Molecule Included in a Half-Spherical Vanadium-Oxide Molecule(2021年06月26日)
  • SYNTHESIS AND OXIDATION CATALYSIS OF FLUORIDE-CONTAINING POLYOXOVANADATES(conference:The 8th Asia-Pacific Congress on Catalysis )(2019年08月05日)
  • Synthesis and Characterization of Multinuclear Cobalt Containing Polyoxovanadates(2019年10月17日)
  • Host-Guest Interaction Inducing a Structure Conversion of a Bowl-Type Dodecavanadate(2019年10月17日)
  • Structure Transformation and Host Property of a Dodecavanadate(conference:7th Asian Conference on Coordination Chemistry)(2019年10月17日)
  • Host-guest property of half spherical type dodecavanadates(conference:The 8th Tokyo Conference on Advanced Catalytic Science and Technology)(2018年08月05日)
  • Synthesis and Characterization of Fluoride-incorporated Polyoxovanadates(conference:International symposium on Metal-Oxo Cluster Sciences: Exploring Novel Possibilities)(2018年08月05日)
  • Host-Guest Property and Reversible Structure Transformation of Dodecavanadates(conference:43rd International Conference on Coordination Chemistry)(2018年07月31日)
  • Structure adaptation of yttrium containing polyoxovanadates(conference:43rd International Conference on Coordination Chemistry)(2018年07月31日)
  • Synthesis and Catalysis of a Titanium-Containing Polyoxovanadate (2017年03月16日)
  • Host Property for the Neutral Molecule Guest of the Bowl-type Dodecavanadate (2016年09月10日)
  • Halide Incorporation Reaction into a Bowl-Type Dodecavanadate(conference:The 10th International Vanadium Symposium)(2016年11月06日)
  • Synthesis of Di- and Trinuclear Manganese Cores Surrounded by Circular Decavanadates(conference:The 10th International Vanadium Symposium)(2016年11月06日)
  • The Movement of the Vanadium-oxygen Mitt(conference:The 10th International Vanadium Symposium)(2016年11月06日)
  • An Yttrium-Containing Polyoxovanadate for Cyanosilylation of Carbonyl Compounds(conference:20th The International Symposium on Homogeneous Catalysis)(2016年07月12日)

Others

Arts and Fieldwork

Patent

Theme to the desired joint research

Grant-in-Aid for Scientific Research

Competitive research funding,Contribution

Collaborative research,Consignment study

Classes (Bachelors)

しろまるInorganic Chemistry A(2023)
しろまるInorganic Chemistry B(2023)
しろまるSpecialized Topics in Chemistry(2023)
しろまるExperiments in Basic Chemistry B(2023)
しろまるResearch Work in Chemistry(2023)
しろまるSpecialized Topics in Material Chemistry(2023)
しろまるLiterature Survey in Chemistry(2023)
しろまるExperiments in Basic Chemistry B(2023)
しろまるGS English Language for Undergraduates II (English for Science and Engineering)(2023)
しろまるGS English Language for Undergraduates I (English for Science and Engineering)(2023)
しろまるExperiments in Fundamental Chemistry(2023)
しろまるExperiments in Fundamental Chemistry(2023)
しろまるInorganic Chemistry A(2022)
しろまるExperiments in Basic Chemistry A(2022)
しろまるInorganic Chemistry B(2022)
しろまるExperiments in Basic Chemistry B(2022)
しろまるExperiments in Basic Chemistry A(2022)
しろまるExperiments in Basic Chemistry B(2022)
しろまるChemistry for Education(2021)
しろまるInorganic Chemistry II(2021)
しろまるChemistry for Education(2021)
しろまるExperiments in Basic Chemistry B(2021)
しろまるInternational Training B(2020)
しろまるInternational Training B(2020)
しろまるInternational Training B(2020)
しろまるInternational Training B(2020)
しろまるExperiments in Basic Chemistry B(2020)
しろまるInorganic Chemistry II(2020)
しろまるExperiments in Basic Chemistry A(2020)
しろまるInternational Training A(2020)
しろまるInternational Training A(2020)
しろまるInternational Training A(2020)
しろまるInternational Training A(2020)
しろまるIntroduction of Chemistry B(2020)
しろまるInternational Training A(2019)
しろまるInternational Training B(2019)
しろまるInternational Training B(2019)
しろまるInternational Training B(2019)
しろまるPresentation and Debate (Freshman Seminar II)(2019)
しろまるInternational Training B(2019)
しろまるInternational Training A(2019)
しろまるExperiments in Basic Chemistry B(2019)
しろまるInorganic Chemistry II(2019)
しろまるInternational Training A(2019)
しろまるInternational Training A(2019)
しろまるExperiments in Basic Chemistry B(2018)
しろまるExperiments in Basic Chemistry B(2017)
しろまるExperiments in Basic Chemistry B(2016)

Classes (Graduate Schools)

しろまるFunctional Molecule Chemistry(2023)
しろまるMaterial Creation Chemistry II(2023)
しろまるInorganic Structural Chemistry(2023)
しろまるLaboratory Rotation I(2023)
しろまるLaboratory Rotation I(2023)
しろまるSeminar in Material Creation(2017)
しろまるSeminar in Material Creation(2017)
しろまるSeminar in Material Creation(2016)
しろまるSeminar in Material Creation(2016)

International Project

International Students

Lecture themes

Others (Social Activities)

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