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August 2025 - Volume 21, Number 4

Re-Os – Clock with Clout

Holly Stein and Laurie Reisberg– Guest Editors

Table of Contents

Thematic Articles

The exceptional power and versatility of the Re-Os radioactive decay system for Earth science stems from the distinctive geochemical behavior of its constituent elements. Here, we first explain how the positions of Re and Os in the periodic table are responsible for their highly siderophile, chalcophile, and organophile properties. We then discuss how these properties dictate the distribution of Re and Os within and at the surface of the Earth and other planetary bodies. Lastly, we describe how the analytical challenges posed by the unusual geochemistry of these elements were overcome with major technological advances, leading to a dramatic decrease in the amount of sample material required for Re-Os isotopic analysis, thereby sparking an explosion of new applications.
Rhenium-osmium geochronology of sulfides and its Os tracer accompaniment have taken their place among geochronometers, although the journey was not without doubters and disparagers. This review highlights several historical hurdles overcome in dating sulfides. The opening act was the debut of molybdenite, which provided an accessible radiometric clock and early insight into the accuracy of the 187Re decay constant. Once controversies surrounding newly minted and game-changing Re-Os molybdenite ages died down, the door flung wide open to begin dating other sulfides, most notably, arsenopyrite and pyrite. Applications sprinted from the ore geology community to constraining the timing of important events, from Earth’s oxygenation to the amalgamation of tectonic terranes. The power of Re-Os sulfide dating in crustal environments was unleashed.
A unique feature of the Re-Os isotope system is its ability to provide precise and accurate depositional ages from organic-rich sedimentary rocks. Applications include geologic timescale calibration, stratigraphic correlation, and dating key events such as biological innovations, mass extinctions, carbon cycle perturbations, Snowball Earth glaciations, and atmospheric oxygenation. Multiple sediment types reveal temporal variations in the osmium isotope composition of seawater, driven by changes in osmium inputs from continental weathering, seafloor hydrothermal systems, and extraterrestrial material. These variations provide valuable information on climate–tectonic interactions, glacial–interglacial cycles, large igneous province magmatism, bolide impacts, and crustal evolution. Continental processes can be inferred from lake sediment records. These diverse applications highlight the central role of the Re-Os isotope pair in understanding Earth’s evolution.
Re-Os geochronology is a powerful tool for unravelling the complexity of petroleum systems. Because of their organophile nature, Re and Os are enriched in sedimentary organic matter and the hydrocarbons it produces upon heating. Rhenium and Os isotopes are used to date hydrocarbon generation, to fingerprint oils, to distinguish different pulses of oil generation, and to determine interactions between oil, host rock, and formation water. Here we summarize knowledge on the content, distribution, and isotopic composition of Re and Os in petroleum and associated waters, highlight the main technical advances for Re-Os analyses, review experimental studies on water–oil interaction, and discuss the diverse Re-Os applications to petroleum systems.
The siderophile elements, which include Re, Pt, Os, and W, directly constrain the accretionary history of Earth. The largely chondritic 186,187Os/188Os ratios of Earth’s mantle, coupled with excesses in siderophile element abundances, provide nearly incontrovertible evidence that some meteoritic addition continued after core formation was complete. Osmium and W isotope systematics of plume-derived mafic-ultramafic rocks reveal the complex chemical evolution of their deep mantle sources. In the upper mantle, Re-Os dating of whole-rock xenoliths and sulfide inclusions in diamonds hosted by kimberlites indicate both ancient melt depletion and subsequent modification of the mantle lithosphere beneath the earliest continents, with Re-Os ages of eclogitic diamonds possibly recording the transition to a sustained plate tectonic regime on Earth.
The 187Re–187Os system offers a unique perspective among the isotopic approaches used to understand planetary evolution because of the chalcophile and siderophile affinities of the parent and daughter elements and their contrasting behaviors during partial melting. Considered the geochronometer of choice to study the Earth’s mantle, from the scale of individual minerals to large-scale outcrops, this system has revealed the survival of Archean and Proterozoic mantle in younger tectonic settings, and has demonstrated local to regional coupling, and sometimes decoupling, between the crust and mantle. Osmium isotopes are also key tracers of melt–peridotite and mantle–crust interactions and recycling processes in subduction zones, and have furthered our understanding of the origin of multi-scale geochemical and isotopic heterogeneities.
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