So, I needed a quick and dirty way to create a dropdown select for hours, minutes and seconds using 2 digit formatting, and to create those arrays of data, I combined range with array merge..
<?php
$prepend = array('00','01','02','03','04','05','06','07','08','09');
$hours = array_merge($prepend,range(10, 23));
$minutes = array_merge($prepend,range(10, 59));
$seconds = $minutes;
?>

Super simple.