Holmium acetylacetonate
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| Names | |
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| Other names
Holmium(III) acetylacetonate
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| Identifiers | |
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3D model (JSmol)
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PubChem CID
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| Properties | |
| C15H21HoO6 | |
| Molar mass | 462.257 g·mol−1 |
| Appearance | yellow-pink[1] |
| Insoluble | |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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3(H2O)2.svg){kind=link}
Chemical compound
Holmium acetylacetonate is a coordination compound with the formula Ho(C5H7O2)3. This anhydrous acetylacetonate complex is often discussed but unlikely to exist per se. The 8-coordinated dihydrate Ho(C5H7O2)3(H2O)2 is a more plausible formula based on the behavior of other lanthanide acetylacetonates. The dihydrate has been characterized by X-ray crystallography.[1]
Attempts to dehydrate other lanthanide acetylacetonates results in decomposition.[2]
Further reading
- R. G. Bulgakov, S. P. Kuleshov, R. R. Vafin, A. G. Ibragimov, U. M. Dzhemilev (2008年03月01日). "Reactions of lanthanide acetylacetonates with triethylaluminum". Kinetics and Catalysis. 49 (2): 299–304. doi:10.1134/S0023158408020195. ISSN 0023-1584. S2CID 97171472 . Retrieved 2021年09月20日.
{{cite journal}}: CS1 maint: multiple names: authors list (link) - Kent J. Eisentraut, Robert E. Sievers (1967年08月01日). "Thermogravimetric studies of metal β-diketonates". Journal of Inorganic and Nuclear Chemistry. 29 (8): 1931–1936. doi:10.1016/0022-1902(67)80452-4. Archived from the original on 2018年06月12日. Retrieved 2021年09月20日.
References
- ^ a b Kooijman, Huub; Nijsen, Frank; Spek, Anthony L.; Schip, Fred van het (2000). "Diaquatris(pentane-2,4-dionato-O,O′)holmium(III) monohydrate and diaquatris(pentane-2,4-dionato-O,O′)holmium(III) 4-hydroxypentan-2-one solvate dihydrate". Acta Crystallographica Section C Crystal Structure Communications. 56 (2): 156–158. doi:10.1107/S0108270199013566 . PMID 10777870.
- ^ Tamang, Sem Raj; Singh, Arpita; Bedi, Deepika; Bazkiaei, Adineh Rezaei; Warner, Audrey A.; Glogau, Keeley; McDonald, Corey; Unruh, Daniel K.; Findlater, Michael (2020). "Polynuclear Lanthanide–Diketonato Clusters for the Catalytic Hydroboration of Carboxamides and Esters". Nat. Catal. 3 (2): 154–162. doi:10.1038/s41929-019-0405-5. S2CID 209897045.
