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I found three georgian encodings:
https://sourceware.org/git/?p=glibc.git;a=blob;f=localedata/charmaps/GEORGIAN-PS;h=64615ff4344d74ea0c70cfd7a6c6c8019afb884e;hb=HEAD
https://sourceware.org/git/?p=glibc.git;a=blob;f=localedata/charmaps/GEORGIAN-ACADEMY;h=9dc1bc9e782e9fe6092a00daf1a75274fd6dd738;hb=HEAD
http://tools.ietf.org/html/draft-giasher-geostd8-00
The first one ("GEORGIAN-PS") is probably the most accurate because it is the one included in the GNU libc.
Could you please try to copy attached georgian_ps.py file into /usr/lib64/python3.3/encodings/ (or /usr/lib/python3.3/encodings/ for 32-bit Linux)?
Then try to print georgian letters using:
 print(bytes(range(0xc0, 0xe6)).decode("GEORGIAN-PS"))
Please give me also your locale encoding:
 import locale; print(locale.getpreferredencoding())
@Caolán: Do you know the GEORGIAN-ACADEMY encoding? It doesn't look to be used by any glibc locale.
On my Fedora 18, I have 3 georgian locales:
* ka_GE.georgianps: locale encoding GEORGIAN-PS
* ka_GE: locale encoding GEORGIAN-PS
* ka_GE.utf8: locale encoding UTF-8
You can workaround this issue by switching your locale from ka_GE.georgianps to ka_GE.utf8.