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Wehn copying os.environ usinf copy.copy(), any manipulation on the copied object will change os.environment, too.
$ python
Python 2.7.3 (default, Apr 22 2012, 07:46:58) 
[GCC 4.6.3] on linux2
Type "help", "copyright", "credits" or "license" for more information.
>>> import copy, os
>>> os.environ['TITI']
Traceback (most recent call last):
 File "<stdin>", line 1, in <module>
 File "/usr/lib/python2.7/UserDict.py", line 23, in __getitem__
 raise KeyError(key)
KeyError: 'TITI'
>>> env = copy.copy(os.environ)
>>> env['TITI'] = 'in den Ferien'
>>> os.environ['TITI']
'in den Ferien'
>>> 
Strictly speaking, this is correct, as the os.environment class is meant to manipulate the environment in the background. But user's expectation is different: he thinks, manipulating the copied object is save and does not effect the environment.