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Which Python 3.2 installation are you using? There are two installers for Python 3.2 for Mac OS X downloadable from python.org, 32-bit-only and 64-bit/32-bit. And which version of Tcl/Tk are you using? Please start IDLE and report the first two lines shown in the "Python Shell" window, for instance:
Python 3.2 (r32:88452, Feb 20 2011, 10:19:59) 
[GCC 4.0.1 (Apple Inc. build 5493)] on darwin
and then show the results of executing the following lines in the IDLE shell:
import _tkinter, subprocess
print(subprocess.getoutput("otool -L " + _tkinter.__file__))
print(subprocess.getoutput("ls -l /Library/Frameworks/Tk.framework/Versions"))