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This looks very related to: http://bugs.python.org/issue13829
I have very simple test code that looks like this:
 import requests
 r = requests.get('http://www.google.com')
 print('requests.get() succeeded')
The above code works fine. However, when:
 
 requests.get('http://www.google.com')
is run inside an rq Queue (redis queue) worker I see this problem.
Any fixes or known workarounds for this?
Process: Python [34628]
Path: /usr/local/Cellar/python3/3.4.3/Frameworks/Python.framework/Versions/3.4/Resources/Python.app/Contents/MacOS/Python
Identifier: Python
Version: 3.4.3 (3.4.3)
Code Type: X86-64 (Native)
Parent Process: Python [34626]
Responsible: Terminal [333]
User ID: 501
Date/Time: 2015年05月24日 08:57:29.055 +0700
OS Version: Mac OS X 10.10.3 (14D136)
Report Version: 11
Anonymous UUID: 341D1B65-8C01-92A4-0CB5-DC7470E594BF
Sleep/Wake UUID: 5DCBEBD5-671C-48C9-8402-765FABE76C61
Time Awake Since Boot: 230000 seconds
Time Since Wake: 4700 seconds
Crashed Thread: 0 Dispatch queue: com.apple.main-thread
Exception Type: EXC_BAD_ACCESS (SIGSEGV)
Exception Codes: KERN_INVALID_ADDRESS at 0x0000000000000110
VM Regions Near 0x110:
-->
 __TEXT 0000000100239000-000000010023b000 [ 8K] r-x/rwx SM=COW /usr/local/Cellar/python3/3.4.3/Frameworks/Python.framework/Versions/3.4/Resources/Python.app/Contents/MacOS/Python
Application Specific Information:
*** multi-threaded process forked ***
crashed on child side of fork pre-exec
Thread 0 Crashed:: Dispatch queue: com.apple.main-thread
0 libdispatch.dylib 	0x00007fff80f9616f _dispatch_async_f_slow + 395
1 com.apple.CoreFoundation 	0x00007fff8c571541 _CFPrefsWithDaemonConnection + 305
2 com.apple.CoreFoundation 	0x00007fff8c540ac6 __80-[CFPrefsSearchListSource generationCountFromListOfSources:count:allowFetching:]_block_invoke + 150
3 com.apple.CoreFoundation 	0x00007fff8c5409d2 -[CFPrefsSearchListSource generationCountFromListOfSources:count:allowFetching:] + 258
4 com.apple.CoreFoundation 	0x00007fff8c3fcea5 -[CFPrefsSearchListSource alreadylocked_copyDictionary] + 133
5 com.apple.CoreFoundation 	0x00007fff8c3f7dba -[CFPrefsSearchListSource alreadylocked_copyValueForKey:] + 42
6 com.apple.CoreFoundation 	0x00007fff8c57211c ___CFPreferencesCopyAppValueWithContainer_block_invoke + 60
7 com.apple.CoreFoundation 	0x00007fff8c53f979 +[CFPrefsSearchListSource withSearchListForIdentifier:container:perform:] + 729
8 com.apple.CoreFoundation 	0x00007fff8c572097 _CFPreferencesCopyAppValueWithContainer + 183
9 com.apple.SystemConfiguration 	0x00007fff8c989dd4 SCDynamicStoreCopyProxiesWithOptions + 153
10 _scproxy.so 	0x0000000100fea8f2 get_proxy_settings + 24
11 org.python.python 	0x00000001002e0c87 PyEval_EvalFrameEx + 18047
12 org.python.python 	0x00000001002e3e8d fast_function + 203
13 org.python.python 	0x00000001002e0b2a PyEval_EvalFrameEx + 17698
14 org.python.python 	0x00000001002e3e8d fast_function + 203
15 org.python.python 	0x00000001002e0b2a PyEval_EvalFrameEx + 17698
16 org.python.python 	0x00000001002e3e8d fast_function + 203
17 org.python.python 	0x00000001002e0b2a PyEval_EvalFrameEx + 17698
18 org.python.python 	0x00000001002e3e8d fast_function + 203
19 org.python.python 	0x00000001002e0b2a PyEval_EvalFrameEx + 17698
20 org.python.python 	0x00000001002e3e8d fast_function + 203
21 org.python.python 	0x00000001002e0b2a PyEval_EvalFrameEx + 17698
22 org.python.python 	0x00000001002dc459 PyEval_EvalCodeEx + 1593
23 org.python.python 	0x000000010026b562 function_call + 372
24 org.python.python 	0x000000010024b12e PyObject_Call + 103
25 org.python.python 	0x00000001002e12d5 PyEval_EvalFrameEx + 19661
26 org.python.python 	0x00000001002dc459 PyEval_EvalCodeEx + 1593
27 org.python.python 	0x000000010026b562 function_call + 372
28 org.python.python 	0x000000010024b12e PyObject_Call + 103
29 org.python.python 	0x00000001002e12d5 PyEval_EvalFrameEx + 19661
30 org.python.python 	0x00000001002dc459 PyEval_EvalCodeEx + 1593
31 org.python.python 	0x00000001002e3f03 fast_function + 321
32 org.python.python 	0x00000001002e0b2a PyEval_EvalFrameEx + 17698
33 org.python.python 	0x00000001002dc459 PyEval_EvalCodeEx + 1593
34 org.python.python 	0x000000010026b562 function_call + 372
35 org.python.python 	0x000000010024b12e PyObject_Call + 103
36 org.python.python 	0x00000001002e12d5 PyEval_EvalFrameEx + 19661
37 org.python.python 	0x00000001002e3e8d fast_function + 203
38 org.python.python 	0x00000001002e0b2a PyEval_EvalFrameEx + 17698
39 org.python.python 	0x00000001002e3e8d fast_function + 203
40 org.python.python 	0x00000001002e0b2a PyEval_EvalFrameEx + 17698
41 org.python.python 	0x00000001002e3e8d fast_function + 203
42 org.python.python 	0x00000001002e0b2a PyEval_EvalFrameEx + 17698
43 org.python.python 	0x00000001002e3e8d fast_function + 203
44 org.python.python 	0x00000001002e0b2a PyEval_EvalFrameEx + 17698
45 org.python.python 	0x00000001002dc459 PyEval_EvalCodeEx + 1593
46 org.python.python 	0x00000001002e3f03 fast_function + 321
47 org.python.python 	0x00000001002e0b2a PyEval_EvalFrameEx + 17698
48 org.python.python 	0x00000001002dc459 PyEval_EvalCodeEx + 1593
49 org.python.python 	0x00000001002dbe1a PyEval_EvalCode + 63
50 org.python.python 	0x00000001002fec3d run_mod + 58
51 org.python.python 	0x00000001002feedc PyRun_FileExFlags + 178
52 org.python.python 	0x00000001002fe6e6 PyRun_SimpleFileExFlags + 865
53 org.python.python 	0x0000000100311856 Py_Main + 3130
54 org.python.python 	0x000000010023ae27 0x100239000 + 7719
55 libdyld.dylib 	0x00007fff830f35c9 start + 1
Thread 0 crashed with X86 Thread State (64-bit):
 rax: 0x0000000101c01080 rbx: 0x0000000000000001 rcx: 0x0000000000000000 rdx: 0x0000000000000100
 rdi: 0x0000000101c00000 rsi: 0x0000000004000000 rbp: 0x00007fff5f9c43d0 rsp: 0x00007fff5f9c43a0
 r8: 0x0000000101c01080 r9: 0x0000000101c00000 r10: 0x0000000000000001 r11: 0x0000000000000202
 r12: 0x00007fff8501347a r13: 0x00007fe581f208c0 r14: 0x00007fff70d23bc0 r15: 0x0000000000001000
 rip: 0x00007fff80f9616f rfl: 0x0000000000010206 cr2: 0x0000000000000110
Logical CPU: 3
Error Code: 0x00000006
Trap Number: 14
Binary Images:
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 0x7fff8d3a2000 - 0x7fff8d3f3fff com.apple.audio.CoreAudio (4.3.0 - 4.3.0) <450293F7-DAE7-3DD0-8F7C-71FC2FD72627> /System/Library/Frameworks/CoreAudio.framework/Versions/A/CoreAudio
 0x7fff8d451000 - 0x7fff8d45eff7 libbz2.1.0.dylib (36) <2DF83FBC-5C08-39E1-94F5-C28653791B5F> /usr/lib/libbz2.1.0.dylib
 0x7fff8d49f000 - 0x7fff8d71eff7 com.apple.CoreData (111 - 526.3) <5A27E0D8-5E5A-335B-B3F6-2601C7B976FA> /System/Library/Frameworks/CoreData.framework/Versions/A/CoreData
 0x7fff8d721000 - 0x7fff8d767ff7 libFontRegistry.dylib (134.1) <CE41D8C2-BEED-345C-BC4F-3775CC06C672> /System/Library/Frameworks/ApplicationServices.framework/Versions/A/Frameworks/ATS.framework/Versions/A/Resources/libFontRegistry.dylib
 0x7fff8d769000 - 0x7fff8d7b8ff7 com.apple.opencl (2.4.2 - 2.4.2) <4A9574ED-15CF-3EBB-B4C0-D30F644D6C74> /System/Library/Frameworks/OpenCL.framework/Versions/A/OpenCL
 0x7fff8d7b9000 - 0x7fff8d7c4ff7 com.apple.CrashReporterSupport (10.10 - 631) <D87A64FA-64B1-3B23-BB43-ADE173C108C6> /System/Library/PrivateFrameworks/CrashReporterSupport.framework/Versions/A/CrashReporterSupport
 0x7fff8da62000 - 0x7fff8da65fff com.apple.xpc.ServiceManagement (1.0 - 1) <9E025823-660A-30C5-A568-223BD595B6F7> /System/Library/Frameworks/ServiceManagement.framework/Versions/A/ServiceManagement
 0x7fff8da85000 - 0x7fff8daa6fff com.apple.framework.Apple80211 (10.3 - 1030716) <D3862426-2586-3DF7-BA75-9A184FCD74C4> /System/Library/PrivateFrameworks/Apple80211.framework/Versions/A/Apple80211
 0x7fff8daa7000 - 0x7fff8dbcfff7 com.apple.coreui (2.1 - 308.6) <DEA5D3E1-D333-302B-A6CF-7643BFDFAED0> /System/Library/PrivateFrameworks/CoreUI.framework/Versions/A/CoreUI
 0x7fff8dd37000 - 0x7fff8dda3fff com.apple.framework.CoreWLAN (5.0 - 500.35.2) <5E228544-77A9-3AA5-8355-E8F6626F50E7> /System/Library/Frameworks/CoreWLAN.framework/Versions/A/CoreWLAN
 0x7fff8dda4000 - 0x7fff8deb6ff7 libvDSP.dylib (516) <151B3CCB-77D3-3715-A3D0-7C74CD5C7FFC> /System/Library/Frameworks/Accelerate.framework/Versions/A/Frameworks/vecLib.framework/Versions/A/libvDSP.dylib
 0x7fff8deca000 - 0x7fff8decdfff com.apple.help (1.3.3 - 46) <CA4541F4-CEF5-355C-8F1F-EA65DC1B400F> /System/Library/Frameworks/Carbon.framework/Versions/A/Frameworks/Help.framework/Versions/A/Help
 0x7fff8dfdb000 - 0x7fff8e0cbfef libJP2.dylib (1237) <A24C99BF-2360-343F-BCA1-F044E78EA0DE> /System/Library/Frameworks/ImageIO.framework/Versions/A/Resources/libJP2.dylib
 0x7fff8e0cc000 - 0x7fff8e14afff com.apple.CoreServices.OSServices (640.4 - 640.4) <20121A5E-7AB5-3624-8CF0-3562F97C8A95> /System/Library/Frameworks/CoreServices.framework/Versions/A/Frameworks/OSServices.framework/Versions/A/OSServices
 0x7fff8e3bc000 - 0x7fff8e3bffff com.apple.IOSurface (97.4 - 97.4) <AE11CFBC-4D46-30F3-BEEC-4C8131079391> /System/Library/Frameworks/IOSurface.framework/Versions/A/IOSurface
 0x7fff8e3c3000 - 0x7fff8e3eefff libc++abi.dylib (125) <88A22A0F-87C6-3002-BFBA-AC0F2808B8B9> /usr/lib/libc++abi.dylib
 0x7fff8e4f2000 - 0x7fff8e616ff7 com.apple.LaunchServices (644.56 - 644.56) <20AABB1C-9319-3E4D-A024-51B0DD5FCD3B> /System/Library/Frameworks/CoreServices.framework/Versions/A/Frameworks/LaunchServices.framework/Versions/A/LaunchServices
 0x7fff8e620000 - 0x7fff8e694ffb com.apple.securityfoundation (6.0 - 55126) <42589E18-D38C-3E25-B638-6E29740C224C> /System/Library/Frameworks/SecurityFoundation.framework/Versions/A/SecurityFoundation
 0x7fff8e695000 - 0x7fff8e6a0ff7 libkxld.dylib (27822048) <28EF8328-E3E2-336A-974B-FB1BF119D55A> /usr/lib/system/libkxld.dylib
 0x7fff8e723000 - 0x7fff8e73cff7 com.apple.CFOpenDirectory (10.10 - 187) <790ED527-EFD2-3EA6-8C97-A8C04E96EBA7> /System/Library/Frameworks/OpenDirectory.framework/Versions/A/Frameworks/CFOpenDirectory.framework/Versions/A/CFOpenDirectory
 0x7fff8e745000 - 0x7fff8e74eff3 com.apple.CommonAuth (4.0 - 2.0) <BA9F5A09-D200-3D18-9F4A-20C789291A30> /System/Library/PrivateFrameworks/CommonAuth.framework/Versions/A/CommonAuth
 0x7fff8e7c3000 - 0x7fff8e7d2fff com.apple.LangAnalysis (1.7.0 - 1.7.0) <D1E527E4-C561-352F-9457-E8C50232793C> /System/Library/Frameworks/ApplicationServices.framework/Versions/A/Frameworks/LangAnalysis.framework/Versions/A/LangAnalysis
 0x7fff8e7d3000 - 0x7fff8e7d5ff7 libsystem_coreservices.dylib (9) <41B7C578-5A53-31C8-A96F-C73E030B0938> /usr/lib/system/libsystem_coreservices.dylib
 0x7fff8e7fc000 - 0x7fff8e7fcff7 libkeymgr.dylib (28) <77845842-DE70-3CC5-BD01-C3D14227CED5> /usr/lib/system/libkeymgr.dylib
 0x7fff8eb0e000 - 0x7fff8eb10fff libRadiance.dylib (1237) <9B048776-53BB-3947-8ECE-9DDA804C86B2> /System/Library/Frameworks/ImageIO.framework/Versions/A/Resources/libRadiance.dylib
 0x7fff8eb1a000 - 0x7fff8ec0cfff libxml2.2.dylib (26) <B834E7C8-EC3E-3382-BC5A-DA38DC4D720C> /usr/lib/libxml2.2.dylib
 0x7fff8ec0d000 - 0x7fff8ec27ff7 com.apple.Kerberos (3.0 - 1) <7760E0C2-A222-3709-B2A6-B692D900CEB1> /System/Library/Frameworks/Kerberos.framework/Versions/A/Kerberos
 0x7fff8eeea000 - 0x7fff8eeeafff com.apple.Carbon (154 - 157) <9BF51672-1684-3FDE-A561-FC59A2864EF8> /System/Library/Frameworks/Carbon.framework/Versions/A/Carbon
 0x7fff8eeeb000 - 0x7fff8ef04ffb com.apple.openscripting (1.4 - 162.1) <E6B42781-A556-355A-8A49-82A8D2B347FF> /System/Library/Frameworks/Carbon.framework/Versions/A/Frameworks/OpenScripting.framework/Versions/A/OpenScripting
 0x7fff8ef05000 - 0x7fff8ef09fff libCoreVMClient.dylib (79.1) <201EF6DF-5074-3CB7-A361-398CF957A264> /System/Library/Frameworks/OpenGL.framework/Versions/A/Libraries/libCoreVMClient.dylib
 0x7fff8ef0a000 - 0x7fff8efb9fe7 libvMisc.dylib (516) <6739E390-46E7-3BFA-9B69-B278562326E6> /System/Library/Frameworks/Accelerate.framework/Versions/A/Frameworks/vecLib.framework/Versions/A/libvMisc.dylib
 0x7fff8f00e000 - 0x7fff8f039fff com.apple.DictionaryServices (1.2 - 229) <F03DFAC6-6285-3176-9C6D-7CC50F8CD52A> /System/Library/Frameworks/CoreServices.framework/Versions/A/Frameworks/DictionaryServices.framework/Versions/A/DictionaryServices
 0x7fff8f06a000 - 0x7fff8f085ff7 libCRFSuite.dylib (34) <D64842BE-7BD4-3D0C-9842-1D202F7C2A51> /usr/lib/libCRFSuite.dylib
 0x7fff8f216000 - 0x7fff8f260ff7 com.apple.HIServices (1.22 - 522.1) <E8BD41E4-7747-3CAF-807A-5CA9AD16B525> /System/Library/Frameworks/ApplicationServices.framework/Versions/A/Frameworks/HIServices.framework/Versions/A/HIServices
 0x7fff8f261000 - 0x7fff8f262fff libsystem_secinit.dylib (18) <581DAD0F-6B63-3A48-B63B-917AF799ABAA> /usr/lib/system/libsystem_secinit.dylib
 0x7fff8f263000 - 0x7fff8f26eff7 com.apple.speech.synthesis.framework (5.3.3 - 5.3.3) <A5640275-E2A6-3856-95EF-5F0DC440B10C> /System/Library/Frameworks/ApplicationServices.framework/Versions/A/Frameworks/SpeechSynthesis.framework/Versions/A/SpeechSynthesis
 0x7fff8f2fc000 - 0x7fff8f302fff com.apple.speech.recognition.framework (5.0.9 - 5.0.9) <BB2D573F-0A01-379F-A2BA-3C454EDCB111> /System/Library/Frameworks/Carbon.framework/Versions/A/Frameworks/SpeechRecognition.framework/Versions/A/SpeechRecognition
 0x7fff8f35e000 - 0x7fff8f3d0fff com.apple.framework.IOKit (2.0.2 - 1050202) <09C0518C-90DF-3FC3-96D6-34D35F72C8EF> /System/Library/Frameworks/IOKit.framework/Versions/A/IOKit
 0x7fff90514000 - 0x7fff9064efff com.apple.ImageIO.framework (3.3.0 - 1237) <3C06213D-847A-3C7B-843E-6EC37113965D> /System/Library/Frameworks/ImageIO.framework/Versions/A/ImageIO
 0x7fff9064f000 - 0x7fff9065fff7 libbsm.0.dylib (34) <A3A2E56C-2B65-37C7-B43A-A1F926E1A0BB> /usr/lib/libbsm.0.dylib
 0x7fff90660000 - 0x7fff90666fff libsystem_trace.dylib (72.20.1) <840F5301-B55A-3078-90B9-FEFFD6CD741A> /usr/lib/system/libsystem_trace.dylib
 0x7fff90747000 - 0x7fff9074bfff com.apple.TCC (1.0 - 1) <CCA42EE2-3400-3444-9486-BC454E60D944> /System/Library/PrivateFrameworks/TCC.framework/Versions/A/TCC
 0x7fff9074c000 - 0x7fff9074eff7 com.apple.securityhi (9.0 - 55006) <5DB5773C-FC07-302C-98FE-4B80D88D481A> /System/Library/Frameworks/Carbon.framework/Versions/A/Frameworks/SecurityHI.framework/Versions/A/SecurityHI
 0x7fff9075a000 - 0x7fff90795fff com.apple.QD (301 - 301) <C4D2AD03-B839-350A-AAF0-B4A08F8BED77> /System/Library/Frameworks/ApplicationServices.framework/Versions/A/Frameworks/QD.framework/Versions/A/QD
 0x7fff90796000 - 0x7fff9079aff7 libGIF.dylib (1237) <8A40FED5-FA90-3E76-A359-CD974C43A962> /System/Library/Frameworks/ImageIO.framework/Versions/A/Resources/libGIF.dylib
External Modification Summary:
 Calls made by other processes targeting this process:
 task_for_pid: 0
 thread_create: 0
 thread_set_state: 0
 Calls made by this process:
 task_for_pid: 0
 thread_create: 0
 thread_set_state: 0
 Calls made by all processes on this machine:
 task_for_pid: 133049
 thread_create: 0
 thread_set_state: 0
VM Region Summary:
ReadOnly portion of Libraries: Total=179.0M resident=138.8M(78%) swapped_out_or_unallocated=40.2M(22%)
Writable regions: Total=82.6M written=5000K(6%) resident=27.3M(33%) swapped_out=0K(0%) unallocated=55.3M(67%)
REGION TYPE VIRTUAL
=========== =======
Dispatch continuations 8192K
Kernel Alloc Once 4K
MALLOC 57.2M
MALLOC (admin) 32K
MALLOC_LARGE (reserved) 384K reserved VM address space (unallocated)
STACK GUARD 4K
Stack 16.1M
VM_ALLOCATE 32K
__DATA 14.7M
__IMAGE 528K
__LINKEDIT 71.9M
__TEXT 107.1M
__UNICODE 552K
shared memory 4K
=========== =======
TOTAL 276.5M
TOTAL, minus reserved VM space 276.2M
Model: MacBookPro12,1, BootROM MBP121.0167.B02, 2 processors, Intel Core i7, 3.1 GHz, 16 GB, SMC 2.28f6
Graphics: Intel Iris Graphics 6100, Intel Iris Graphics 6100, Built-In
Memory Module: BANK 0/DIMM0, 8 GB, DDR3, 1867 MHz, 0x02FE, 0x4544464232333241314D412D4A442D460000
Memory Module: BANK 1/DIMM0, 8 GB, DDR3, 1867 MHz, 0x02FE, 0x4544464232333241314D412D4A442D460000
AirPort: spairport_wireless_card_type_airport_extreme (0x14E4, 0x133), Broadcom BCM43xx 1.0 (7.15.166.24.3)
Bluetooth: Version 4.3.4f4 15601, 3 services, 27 devices, 1 incoming serial ports
Network Service: Wi-Fi, AirPort, en0
Serial ATA Device: APPLE SSD SM1024G, 1 TB
USB Device: Hub
USB Device: Hub
USB Device: Internal Memory Card Reader
USB Device: Hub
USB Device: Hub
USB Device: Bluetooth USB Host Controller
Thunderbolt Bus: MacBook Pro, Apple Inc., 27.1

One workaround should be to disable network proxy lookups by defining the environment variable 'no_proxy' with value '*' in the Python process, for example:
env no_proxy='*' python3.4 ...

Thanks! That does work.
I'm concerned there may be unintended or undesired consequences of this.
Hope the bug gets fixed, but will use the workaround for now.