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Resistance management for sustainable agriculture and improved public health

The IRAC Mode of Action Classification Online

The definitive, global scheme on the target sites of acaricides and insecticides.

Effective IRM strategies: Sequences or alternations of MoA

Effective insecticide resistance management (IRM) strategies seek to minimise the selection of resistance to any one type of insecticide. In practice, alternations, sequences or rotations of compounds from different MoA groups provide sustainable and effective IRM. Applications are often arranged into MoA spray windows or blocks that are defined by the stage of crop development and the biology of the lepidopteran species of concern. Local expert advice should always be followed with regard to spray windows and timing. Several sprays may be possible within each spray window, but it is generally essential that successive generations of the pest are not treated with compounds from the same MoA group. Metabolic resistance mechanisms may give cross-resistance between MoA groups; where this is known to occur, the above advice should be modified accordingly.

Jump to colour key
  • 1 Acetylcholinesterase (AChE) inhibitors

    Inhibit AChE, causing hyperexcitation. AChE is the enzyme that terminates the action of the excitatory neurotransmitter acetylcholine at nerve synapses.

    View Acetylcholinesterase (AChE) inhibitors Molecular Structure

    ACarbamates

    • Alanycarb
    • Aldicarb
    • Bendiocarb
    • Benfuracarb
    • Butocarboxim
    • Butoxycarboxim
    • Carbaryl
    • Carbofuran
    • Carbosulfan
    • Ethiofencarb
    • Fenobucarb
    • Formetanate
    • Furathiocarb
    • Isoprocarb
    • Methiocarb
    • Methomyl
    • Metolcarb
    • Oxamyl
    • Pirimicarb
    • Propoxur
    • Thiodicarb
    • Thiofanox
    • Triazamate
    • Trimethacarb
    • XMC
    • Xylylcarb

    BOrganophosphates

    • Acephate
    • Azamethiphos
    • Azinphos-ethyl
    • Azinphos-methyl
    • Cadusafos
    • Chlorethoxyfos
    • Chlorfenvinphos
    • Chlormephos
    • Chlorpyrifos
    • Chlorpyrifos-methyl
    • Coumaphos
    • Cyanophos
    • Demeton-S-methyl
    • Diazinon
    • Dichlorvos/ DDVP
    • Dicrotophos
    • Dimethoate
    • Dimethylvinphos
    • Disulfoton
    • EPN
    • Ethion
    • Ethoprophos
    • Famphur
    • Fenamiphos
    • Fenitrothion
    • Fenthion
    • Fosthiazate
    • Heptenophos
    • Isofenphos
    • Isoxathion
    • Malathion
    • Mecarbam
    • Methamidophos
    • Methidathion
    • Mevinphos
    • Monocrotophos
    • Naled
    • Omethoate
    • Oxydemeton-methyl
    • Parathion
    • Parathion-methyl
    • Phenthoate
    • Phosalone
    • Phorate
    • Phosmet
    • Phosphamidon
    • Phoxim
    • Profenofos
    • Propetamphos
    • Prothiofos
    • Pyraclofos
    • Pyridaphenthion
    • Quinalphos
    • Sulfotep
    • Tebupirimfos
    • Temephos
    • Terbufos
    • Tetrachlorvinphos
    • Thiometon
    • Triazophos
    • Trichlorfon
    • Vamidothion
    • Pirimiphos-methyl
    • Imicyafos
    • Isopropyl O-(methoxyaminothio-phosphoryl) salicylate
  • 2 GABA-gated chloride channel blockers

    Block the GABA-activated chloride channel, causing hyperexcitation and convulsions. GABA is the major inhibitory neurotransmitter in insects.

    View GABA-gated chloride channel blockers Molecular Structure

    ACyclodiene organochlorines

    • Chlordane
    • Endosulfan

    BPhenylpyrazoles (Fiproles)

    • Ethiprole
    • Fipronil
  • 3 Sodium channel modulators

    Keep sodium channels open, causing hyperexcitation and, in some cases, nerve block. Sodium channels are involved in the propagation of action potentials along nerve axons.

    View Sodium channel modulators Molecular Structure

    APyrethroids, Pyrethrins

    • Acrinathrin
    • Allethrin
    • d-cis-trans Allethrin
    • d-trans Allethrin
    • Bifenthrin
    • Bioallethrin
    • Bioallethrin S-cyclopentenyl
    • Bioresmethrin
    • Cycloprothrin
    • Cyfluthrin
    • beta-Cyfluthrin
    • Cyhalothrin
    • lambda-Cyhalothrin
    • gamma-Cyhalothrin
    • Cypermethrin
    • alpha-Cypermethrin
    • beta-Cypermethrin
    • theta-Cypermethrin
    • zeta-Cypermethrin
    • Cyphenothrin [(1R)-trans- isomers]
    • Deltamethrin
    • Empenthrin [(EZ)- (1R)- isomers]
    • Esfenvalerate
    • Etofenprox
    • Fenpropathrin
    • Fenvalerate
    • Flucythrinate
    • Flumethrin
    • tau-Fluvalinate
    • Kadethrin
    • Pyrethrins (pyrethrum)
    • Halfenprox
    • Phenothrin [(1R)-trans- isomer]
    • Prallethrin
    • Resmethrin
    • Silafluofen
    • Tefluthrin
    • Tetramethrin
    • Tetramethrin [(1R)- isomers]
    • Tralomethrin
    • Transfluthrin
    • Permethrin

    BDDT, Methoxychlor

    • DDT
    • Methoxychlor
  • 4 Nicotinic acetylcholine receptor (nAChR) competitive modulators

    Bind to the acetylcholine site on nAChRs, causing a range of symptoms from hyper-excitation to lethargy and paralysis. Acetylcholine is the major excitatory neurotransmitter in the insect central nervous system.

    View Nicotinic acetylcholine receptor (nAChR) competitive modulators Molecular Structure

    ANeonicotinoids

    • Acetamiprid
    • Clothianidin
    • Dinotefuran
    • Imidacloprid
    • Nitenpyram
    • Thiacloprid
    • Thiamethoxam

    BNicotine

    • Nicotine

    CSulfoximines

    • Sulfoxaflor

    DButenolides

    • Flupyradifurone

    EMesoionics

    • Triflumezopyrim
    • Dicloromezotiaz
    • Fenmezoditiaz

    FPyridylidenes

    • Flupyrimin
  • 5 Nicotinic acetylcholine receptor (nAChR) allosteric modulators - Site I

    Allosterically activate nAChRs, causing hyperexcitation of the nervous system. Acetylcholine is the major excitatory neurotransmitter in the insect central nervous system.

    View Nicotinic acetylcholine receptor (nAChR) allosteric modulators - Site I Molecular Structure

    Spinosyns

    • Spinetoram
    • Spinosad
  • 6 Glutamate-gated chloride channel (GluCl) allosteric modulators

    Allosterically activate glutamate-gated chloride channels (GluCls), causing paralysis. Glutamate is an important inhibitory neurotransmitter in insect.

    View Glutamate-gated chloride channel (GluCl) allosteric modulators Molecular Structure

    Avermectins, Milbemycins

    • Abamectin
    • Emamectin benzoate
    • Lepimectin
    • Milbemectin
  • 7 Juvenile hormone receptor modulators

    Applied in the pre-metamorphic instar, these compounds disrupt and prevent metamorphosis.

    View Juvenile hormone receptor modulators Molecular Structure

    AJuvenile hormone analogues

    • Hydroprene
    • Kinoprene
    • Methoprene

    BFenoxycarb

    • Fenoxycarb

    CPyriproxyfen

    • Pyriproxyfen
  • 8 Miscellaneous non-specific (multi-site) inhibitors

    AAlkyl halides

    • Methyl bromide and other alkyl halides
    • 1,3-dichloropropene

    BChloropicrin

    • Chloropicrin

    CFluorides

    • Cryolite
    • Sulfuryl fluoride

    DBorates

    • Borax
    • Boric acid
    • Disodium octaborate
    • Sodium borate
    • Sodium metaborate

    ETartar emetic

    • Tartar emetic

    FMethyl isothiocyanate generators

    • Dazomet
    • Metam
    • Methyl isothiocyanate
  • 9 Chordotonal Organ TRPV Channel Modulators

    Bind to and disrupt the gating of Nan-Iav TRPV (Transient Receptor Potential Vanilloid) channel complexes in chrodotonal stretch receptor organs, which are critical for the senses of hearing, gravity, balance, acceleration, proprioception and kinesthesia. This disrupts feeding and other behaviors in target insects.

    View Chordotonal Organ TRPV Channel Modulators Molecular Structure

    Bpyridine azomethine derivatives

    • Pymetrozine
    • Pyrifluquinazon

    DPyropenes

    • Afidopyropen
  • 10 Mite growth inhibitors affecting CHS1

    Inhibit the enzyme that catalyzes the polymerization of Chitin.

    View Mite growth inhibitors affecting CHS1 Molecular Structure

    AClofentezine, Diflovidazin, Hexythiazox

    • Clofentezine
    • Diflovidazin
    • Hexythiazox

    BEtoxazole

    • Etoxazole
  • 11 Microbial disruptors of insect midgut membranes

    Protein toxins that bind to receptors on the midgut membrane and induce pore formation, resulting in ionic imbalance and septicemia.

    View Microbial disruptors of insect midgut membranes Molecular Structure

    ABacillus thuringiensis and the insecticidal proteins they produce

    • B.t. var. israelensis
    • B.t. var. aizawai
    • B.t. var. kurstaki
    • B.t. var. tenebrionensis

    BBacillus sphaericus

    • Bacillus sphaericus
  • 12 Inhibitors of mitochondrial ATP synthase

    ADiafenthiuron

    • Diafenthiuron

    BOrganotin miticides

    • Azocyclotin
    • Cyhexatin
    • Fenbutatin oxide

    CPropargite

    • Propargite

    DTetradifon

    • Tetradifon
  • 13 Uncouplers of oxidative phosphorylation via disruption of the proton gradient

    Protonophores that short-circuit the mitochondrial proton gradient so that ATP can not be synthesized.

    View Uncouplers of oxidative phosphorylation via disruption of the proton gradient Molecular Structure

    Pyrroles, Dinitrophenols, Sulfluramid

    • Chlorfenapyr
    • DNOC
    • Sulfluramid
  • 14 Nicotinic acetylcholine receptor (nAChR) channel blockers

    Block the nAChR ion channel, resulting in nervous system block and paralysis. Acetylcholine is the major excitatory neurotransmitter in the insect central nervous system.

    View Nicotinic acetylcholine receptor (nAChR) channel blockers Molecular Structure

    Nereistoxin analogues

    • Bensultap
    • Cartap hydrochloride
    • Thiocyclam
    • Thiosultap-sodium
  • 15 Inhibitors of chitin biosynthesis affecting CHS1

    Inhibit the enzyme that catalyzes the polymerization of Chitin.

    View Inhibitors of chitin biosynthesis affecting CHS1 Molecular Structure

    Benzoylureas

    • Bistrifluron
    • Chlorfluazuron
    • Diflubenzuron
    • Flucycloxuron
    • Flufenoxuron
    • Hexaflumuron
    • Lufenuron
    • Novaluron
    • Noviflumuron
    • Teflubenzuron
    • Triflumuron
  • 16 Inhibitors of chitin biosynthesis, type 1

    Incompletely defined MoA leading to inhibition of chitin biosynthesis in a number of insects, including whiteflies.

    View Inhibitors of chitin biosynthesis, type 1 Molecular Structure

    Buprofezin

    • Buprofezin
  • 17 Moulting disruptor, Dipteran

    Incompletely defined MoA that leads to moult disruption.

    View Moulting disruptor, Dipteran Molecular Structure

    Cyromazine

    • Cyromazine
  • 18 Ecdysone receptor agonists

    Mimic the moulting hormone, ecdysone, inducing a precocious moult.

    View Ecdysone receptor agonists Molecular Structure

    Diacylhydrazines

    • Chromafenozide
    • Halofenozide
    • Methoxyfenozide
    • Tebufenozide
  • 19 Octopamine receptor agonists

    Activate octopamine receptors, leading to hyperexcitation. Octopamine is the insect equivalent of adrenaline, the fight-or-flight neurohormone.

    View Octopamine receptor agonists Molecular Structure

    Amitraz

    • Amitraz
  • 20 Mitochondrial complex III electron transport inhibitors – Qo site

    Inhibit electron transport complex III, preventing the utilization of energy by cells.

    View Mitochondrial complex III electron transport inhibitors – Qo site Molecular Structure

    AHydramethylnon

    • Hydramethylnon

    BAcequinocyl

    • Acequinocyl

    CFluacrypyrim

    • Fluacrypyrim

    DBifenazate

    • Bifenazate
  • 21 Mitochondrial complex I electron transport inhibitors

    Inhibit electron transport complex I, preventing the utilization of energy by cells.

    View Mitochondrial complex I electron transport inhibitors Molecular Structure

    AMETI acaricides and insecticides

    • Fenazaquin
    • Fenpyroximate
    • Pyrimidifen
    • Pyridaben
    • Tebufenpyrad
    • Tolfenpyrad

    BRotenone

    • Rotenone
  • 22 Voltage-dependent sodium channel blockers

    Block sodium channels, causing nervous system shutdown and paralysis.
    Sodium channels are involved in the propagation of action potentials along nerve axons.

    View Voltage-dependent sodium channel blockers Molecular Structure

    AOxadiazines

    • Indoxacarb

    BSemicarbazones

    • Metaflumizone
  • 23 Inhibitors of acetyl-CoA carboxylase

    Inhibit acetyl coenzyme A carboxylase, part of the first step in lipid biosynthesis, leading to insect death.

    View Inhibitors of acetyl-CoA carboxylase Molecular Structure

    Tetronic and Tetramic acid derivatives

    • Spirodiclofen
    • Spiromesifen
    • Spiropidion
    • Spirotetramat
    • Spidoxamat
  • 24 Mitochondrial complex IV electron transport inhibitors

    Inhibit electron transport complex IV, preventing the utilization of energy by cells.

    View Mitochondrial complex IV electron transport inhibitors Molecular Structure

    APhosphides

    • Aluminium phosphide
    • Calcium phosphide
    • Phosphine
    • Zinc phosphide

    BCyanides

    • Calcium cyanide
    • Potassium cyanide
    • Sodium cyanide
  • 25 Mitochondrial complex II electron transport inhibitors

    Inhibit electron transport complex II, preventing utilization of energy by cells.

    View Mitochondrial complex II electron transport inhibitors Molecular Structure

    ABeta-ketonitrile derivatives

    • Cyenopyrafen
    • Cyflumetofen

    BCarboxanilides

    • Pyflubumide
  • 28 Ryanodine receptor modulators

    Activate muscle ryanodine receptors, leading to contraction and paralysis. Ryanodine receptors mediate calcium release into the cytoplasm from intracellular stores.

    View Ryanodine receptor modulators Molecular Structure

    Diamides

    • Chlorantraniliprole
    • Cyantraniliprole
    • Cyclaniliprole
    • Flubendiamide
    • Tetraniliprole
  • 29 Chordotonal organ nicotinamidase inhibitors

    Disrupt the function of chrodotonal stretch receptor organs, which are critical for the senses of hearing, gravity, balance, acceleration, proprioception and kinesthesia. This disrupts feeding and other behaviors in target insects. In contrast to Group 9, Group 29 insecticides do not bind to the Nan-lav TRPV channel complex.

    View Chordotonal organ nicotinamidase inhibitors Molecular Structure

    Flonicamid

    • Flonicamid
  • 30 GABA-gated chloride channel allosteric modulators

    Allosterically inhibit the GABA-activated chloride channel, causing hyperexcitation and convulsions. GABA is the major inhibitory neurotransmitter in insects.

    View GABA-gated chloride channel allosteric modulators Molecular Structure

    Meta-diamides, Isoxazolines

    • Broflanilide
    • Fluxametamide
    • Isocycloseram
  • 31 Baculoviruses

    A baculovirus-unique Per os Infectivity Factor (PIF) protein complex on the virus promotes host-specific infection by binding to PIF targets on midgut cells that are unknown but believed to be unique for each baculovirus type. Infection is ultimately lethal.

    View Baculoviruses Molecular Structure

    Granuloviruses (GVs), Nucleopolyhedroviruses (NPVs)

    • Cydia pomonella GV
    • Thaumatotibia leucotreta GV
    • Anticarsia gemmatalis MNPV
    • Helicoverpa armigera NPV
  • 32 Nicotinic Acetylcholine Receptor (nAChR) Allosteric Modulators - Site II

    Allosterically activate nAChRs (at a site distinct from Group 5 - Site I), causing hyperexcitation of the nervous system. Acetylcholine is the major excitatory neurotransmitter in the insect central nervous system.

    View Nicotinic Acetylcholine Receptor (nAChR) Allosteric Modulators - Site II Molecular Structure

    GS-omega/kappa HXTX-Hv1a peptide

    • GS-omega/kappa HXTX-Hv1a peptide
  • 33 Calcium‐activated potassium channel (KCa2) modulators

    Negative modulation of KCa2 causes hyperexcitation and convulsions. KCa2 channels are activated by increase of the intracellular calcium concentration and are involved in the regulation of action potentials.

    View Calcium‐activated potassium channel (KCa2) modulators Molecular Structure

    Acynonapyr

    • Acynonapyr
  • 34 Mitochondrial complex III electron transport inhibitors – Qi site

    Inhibit electron transport complex III, preventing the utilization of energy by cells. In contrast to Group 20, Group 34 insecticides bind to the Qi site.

    View Mitochondrial complex III electron transport inhibitors – Qi site Molecular Structure

    Flometoquin

    • Flometoquin
  • 35 RNA Interference mediated target suppressors

    Multiple biological processes govern the accumulation of proteins critical to supporting a wide variety of functions within insects. Protein suppressors act through reduction of specific protein levels in the pest species. Insecticides that act in this manner are generally moderately slow acting.

    View RNA Interference mediated target suppressors Molecular Structure

    Ledprona

    • Ledprona
  • 36 Chordotonal organ modulators – undefined target site

    Disrupt the function of chordotonal stretch receptor organs, which are critical for the senses of hearing, gravity, balance, acceleration, proprioception and kinesthesia. This disrupts feeding and other behaviors in target insects. Group 36 insecticides act at a site different from Group 9 and Group 29 insecticides and are neither affecting TRPV channels nor nicotinamidase.

    View Chordotonal organ modulators – undefined target site Molecular Structure

    Pyridazine pyrazolecarboxamides

    • Dimpropyridaz
  • 37 Vesicular acetylcholine transporter (VAChT) inhibitor

    Bind to VAChTs, causing cholinergic synaptic transmission block resulting in nervous system shutdown and paralysis. VAChTs are involved in loading acetylcholine into synaptic vesicles

    View Vesicular acetylcholine transporter (VAChT) inhibitor Molecular Structure

    Oxazosulfyl

    • Oxazosulfyl
  • UN Compounds of unknown or uncertain MoA

    Azadirachtin

    • Azadirachtin

    Benzoximate

    • Benzoximate

    Benzpyrimoxan

    • Benzpyrimoxan

    Bromopropylate

    • Bromopropylate

    Chinomethionat

    • Chinomethionat

    Dicofol

    • Dicofol

    Lime sulfur

    • Lime Sulfur

    Mancozeb

    • Mancozeb

    Pyridalyl

    • Pyridalyl

    Sulfur

    • Sulfur
  • UNB Bacterial agents (non-Bt) of unknown or uncertain MoA

    [Class not defined]

    • Burkholderia spp
    • Wolbachie pipientis (Zap)
  • UNE Botanical essence including synthetic, extracts and unrefined oils with unknown or uncertain MoA

    [Class not defined]

    • Chenopodium ambrosioides near ambrosioides extract
    • Fatty acid monoesters with glycerol or propanediol
    • Neem oil
    • Nonanoic acid
    • Sabadilla Extract
  • UNF Fungal agents of unknown or uncertain MoA

    [Class not defined]

    • Beauveria bassiana strains
    • Metarhizium brunneum strain F52
    • Paecilomyces fumosoroseus Apopka strain 97
    • Akanthomyces muscarius Ve6
  • UNM Non-specific mechanical and physical disruptors

    [Class not defined]

    • Diatomaceous earth
    • Mineral Oil
    • Polydimethylsiloxane (PDMS)
  • UNP Peptides of unknown or uncertain MoA

  • UNV Viral agents (non-baculovirus) of unknown or uncertain MoA

Modes of action are colour-coded according to the physiological functions affected. This informs the symptomology, speed of action and other properties of the actives therein and not for any resistance management purpose. Base rotations for resistance management on the mode of action number only.

  • Nerve & Muscle Most current insecticides act on nerve and muscle targets. Insecticides that act on these targets are generally fast acting.
  • Growth Insect development is controlled by juvenile hormone and ecdysone, by directly perturbing cuticle formation/deposition or lipid biosynthesis. Such insect growth regulators are generally slow to moderately slow acting.
  • Respiration Several insecticides are known to interfere with mitochondrial respiration by the inhibition of electron transport and/or oxidative phosphorylation. Such insecticides are generally fast to moderately fast acting.
  • Midgut Lepidopteran-specific microbial toxins that are sprayed or expressed in transgenic crop varieties.
  • Protein Suppressors Multiple biological processes govern the accumulation of proteins critical to supporting a wide variety of functions within insects. Protein suppressors act through reduction of specific protein levels in the pest species. Insecticides that act in this manner are generally moderately slow acting.
  • Unknown or Non-Specific Several insecticides are known to affect less well-described target-sites or functions, or to act non-specifically on multiple targets.

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